Review and analysis of nanostructured olivine-based lithium recheargeable batteries: Status and trends

被引：171

作者：

Zaghib, K. ^{[1
]}

Guerfi, A. ^{[1
]}

Hovington, P. ^{[1
]}

Vijh, A. ^{[1
]}

Trudeau, M. ^{[1
]}

Mauger, A. ^{[2
]}

Goodenough, J. B. ^{[3
]}

Julien, C. M. ^{[4
]}

机构：

[1] Inst Rech Hydroquebec IREQ, Varennes, PQ J3X 1S1, Canada

[2] Univ Paris 06, IMPMC, F-75005 Paris, France

[3] Univ Texas Austin, Austin, TX 78712 USA

[4] Univ Paris 06, F-75005 Paris, France

来源：

JOURNAL OF POWER SOURCES | 2013年 / 232卷

关键词：

Nanostructed material; Olivines; Cathode; Li-ion; Li rechargeable batteries; ADVANCED CATHODE MATERIAL; ELECTROCHEMICAL PERFORMANCE; PHOSPHO-OLIVINES; ELECTRON-MICROSCOPY; MAGNETIC-PROPERTIES; POSITIVE-ELECTRODE; MISCIBILITY GAP; PARTICLE-SIZE; LI2MSIO4; M; LIFEPO4;

D O I：

10.1016/j.jpowsour.2012.12.095

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

LiFePO4 has emerged as the winning cathode material for a new generation of Li-ion batteries that are increasingly used for hybrid and electric vehicles, due to its remarkable electrochemical properties. The present review gives the state of the art in the understanding of the properties of this material and the other members of the same family. We discuss the effects of the decrease of the size of the particles down to circa 20 nm; some of them have been misunderstood or are still open questions. All of them are important to determine the trends in the research and development on this family of materials in the future. The cells' properties are also reviewed with both the graphite and more recently the Li4Ti5O12 anodes, the last one providing outstanding performance in terms of cycling life and power that make them promising not only for electric vehicles, but also to solve for intermittence locally in smart grids. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：357 / 369

页数：13

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