ADMET: The Future Revealed

被引:162
作者
Atallah, Pascale
Wagener, Kenneth B. [1 ]
Schulz, Michael D.
机构
[1] Univ Florida, Dept Chem, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA
基金
美国国家科学基金会;
关键词
ACYCLIC DIENE METATHESIS; IMIDO ALKYLIDENE COMPLEXES; METAL-CONTAINING POLYMERS; OLEFIN METATHESIS; MOLECULAR-WEIGHT; RENEWABLE RESOURCES; CHIRAL POLYOLEFINS; PRECISE SYNTHESIS; BLOCK-COPOLYMERS; BAND-GAP;
D O I
10.1021/ma400067b
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Olefin metathesis has been embraced by polymer chemists as a method for creating well-defined polymers. In particular, ADMET and ROMP have emerged as the primary modes of metathesis polymerization. ADMET reactions are now common, found in textbooks, and easy to perform if the proper techniques are chosen. Much remains to be done, however, with work now focusing on silicon chemistry, direct control of tacticity in precision polymers, biological applications, modeling crystal lattices in common polyolefins, exploring solid-state metathesis reactions, and creating water-soluble ADMET polymers.
引用
收藏
页码:4735 / 4741
页数:7
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