Diffusion barrier properties of TaNx films prepared by plasma enhanced atomic layer deposition from PDMAT with N2 or NH3 plasma

被引:21
作者
Xie, Qi [1 ,2 ]
Musschoot, Jan [2 ]
Detavernier, Christophe [2 ]
Deduytsche, Davy [2 ]
Van Meirhaeghe, Roland L. [2 ]
Van den Berghe, Sven [3 ]
Jiang, Yu-Long [1 ]
Ru, Guo-Ping [1 ]
Li, Bing-Zong [1 ]
Qu, Xin-Ping [1 ]
机构
[1] Fudan Univ, Dept Microelect, State Key Lab ASIC & Syst, Shanghai 200433, Peoples R China
[2] Univ Ghent, Dept Solid State Sci, B-9000 Ghent, Belgium
[3] CEN SCK, Belgian Nucl Res Ctr, LHMA, B-2400 Mol, Belgium
基金
中国国家自然科学基金;
关键词
Atomic layer deposition; TaN; Diffusion barrier; Cu metallization;
D O I
10.1016/j.mee.2008.05.026
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Carbon free TaNx films were deposited by plasma enhanced atomic layer deposition (PEALD) using a combination of pentakis(dimethylamino)Ta (PDMAT) and either N-2 or NH3 plasma. Good linearity and saturation behavior were observed for the TaNx films grown with NH3 plasma while non-ideal saturation features were observed for the films grown with N-2 plasma. The thermal stability of the TaN, films could be improved by reducing the pressure of the reactants and by increasing the plasma exposure time. The TaNx films deposited using N-2 plasma exhibit better diffusion barrier properties than the films deposited using NH3 plasma. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:2059 / 2063
页数:5
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