Proton Conduction in Metal-Organic Frameworks and Related Modularly Built Porous Solids

被引：657

作者：

Yoon, Minyoung ^{[1
,2
]}

Suh, Kyungwon ^{[1
,2
]}

Natarajan, Srinivasan ^{[1
,2
,3
]}

Kim, Kimoon ^{[1
,2
]}

机构：

[1] Pohang Univ Sci & Technol, Div Adv Mat Sci, Ctr Smart Supramol, Pohang, South Korea

[2] Pohang Univ Sci & Technol, Dept Chem, Pohang, South Korea

[3] Indian Inst Sci, Framework Solids Lab, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 10期

基金：

新加坡国家研究基金会;

关键词：

coordination polymers; fuel cells; metal-organic frameworks; porous materials; proton conduction; POLYMER ELECTROLYTE MEMBRANES; COPPER COORDINATION POLYMER; FUNCTIONALIZED ZEOLITE-BETA; IONIC LIQUID; MESOPOROUS SILICA; TRANSPORT; ACID; DIFFUSION; IMIDAZOLE; MECHANISM;

D O I：

10.1002/anie.201206410

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Proton-conducting materials are an important component of fuel cells. Development of new types of proton-conducting materials is one of the most important issues in fuel-cell technology. Herein, we present newly developed proton-conducting materials, modularly built porous solids, including coordination polymers (CPs) or metalorganic frameworks (MOFs). The designable and tunable nature of the porous materials allows for fast development in this research field. Design and synthesis of the new types of proton-conducting materials and their unique proton-conduction properties are discussed.

引用

页码：2688 / 2700

页数：13

共 122 条

[91] Very large breathing effect in the first nanoporous chromium(III)-based solids:: MIL-53 or CrIII(OH)•{O2C-C6H4-CO2}•{HO2C-C6H4-CO2H}x•H2Oy [J].