Conversion of Guaiacol over Supported Ru Catalysts

被引：109

作者：

Boonyasuwat, Sunya ^{[1
]}

Omotoso, Taiwo ^{[1
]}

Resasco, Daniel E. ^{[1
]}

Crossley, Steven P. ^{[1
]}

机构：

[1] Univ Oklahoma, Sch Chem Biol & Mat Engn, Norman, OK 73019 USA

来源：

CATALYSIS LETTERS | 2013年 / 143卷 / 08期

基金：

美国国家科学基金会;

关键词：

Biomass conversion; Ruthenium; Titania; BIOMASS FAST PYROLYSIS; CARBOXYLIC-ACIDS; REACTION NETWORK; ACETIC-ACID; HYDRODEOXYGENATION; OIL; DECOMPOSITION; KETONIZATION; ANISOLE; PHENOL;

D O I：

10.1007/s10562-013-1033-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vapor phase conversion of guaiacol over Ru catalysts supported on C, SiO2, Al2O3, and TiO2 at 400 A degrees C in flowing atmospheric hydrogen is reported. Results indicate a strong synergy between Ru and TiO2 when compared with other catalysts studied as evidenced by enhanced activity for deoxygenation, transalkylation, and decreased deactivation rates. These results are attributed to the enhanced activity of the support brought about by the ability of Ru to reduce TiO2 and create highly active sites for the conversion of guaiacol.

引用

页码：783 / 791

页数：9

共 48 条

[1] CATALYTIC CONVERSION OF A BIOMASS-DERIVED OIL TO FUELS AND CHEMICALS .1. MODEL-COMPOUND STUDIES AND REACTION PATHWAYS [J].

ADJAYE, JD ;

BAKHSHI, NN .

BIOMASS & BIOENERGY, 1995, 8 (03) :131-149

[2] PRODUCTION OF HYDROCARBONS BY CATALYTIC UPGRADING OF A FAST PYROLYSIS BIO-OIL .1. CONVERSION OVER VARIOUS CATALYSTS [J].

ADJAYE, JD ;

BAKHSHI, NN .

FUEL PROCESSING TECHNOLOGY, 1995, 45 (03) :161-183

[3]

Anex R. P., 2009, DIV FUEL CHEM, V54, P704

[4] The transformations involving methanol in the acid- and base-catalyzed gas-phase methylation of phenol [J].

Ballarini, N. ;

Cavani, F. ;

Maselli, L. ;

Montaletti, A. ;

Passeri, S. ;

Scagliarini, D. ;

Flego, C. ;

Perego, C. .

JOURNAL OF CATALYSIS, 2007, 251 (02) :423-436

[5]

Bamberger E., 1910, Chem. Ber, V43, P3517, DOI [10.1002/cber.191004303142, DOI 10.1002/CBER.191004303142]

[6] ALKYLATION OF PHENOL WITH ANISOLE OVER ZEOLITES OR GAMMA-ALUMINA [J].

BELTRAME, P ;

BELTRAME, PL ;

CARNITI, P ;

CASTELLI, A ;

FORNI, L .

APPLIED CATALYSIS, 1987, 29 (02) :327-334

[7]

Bossi A., 1979, Stud. Surf. Sci. Catal, V3, P405, DOI 10.1016/S0167-2991(09)60227-5

[8] INFLUENCE OF THE SUPPORT OF COMO SULFIDE CATALYSTS AND OF THE ADDITION OF POTASSIUM AND PLATINUM ON THE CATALYTIC PERFORMANCES FOR THE HYDRODEOXYGENATION OF CARBONYL, CARBOXYL, AND GUAIACOL-TYPE MOLECULES [J].

CENTENO, A ;

LAURENT, E ;

DELMON, B .

JOURNAL OF CATALYSIS, 1995, 154 (02) :288-298

[9] Epitaxial growth and properties of thin film oxides [J].

Chambers, SA .

SURFACE SCIENCE REPORTS, 2000, 39 (5-6) :105-180

[10] Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites [J].

Cheung, P ;

Bhan, A ;

Sunley, GJ ;

Iglesia, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) :1617-1620

← 1 2 3 4 5 →