The effects of high energy electron beam irradiation in air on accelerated aging and on the structure property relationships of low density polyethylene

The response of low density polyethylene (LDPE) to high energy electron beam irradiation in air (10 MeV) between 25 and 400 kGy was examined and compared to non-irradiated polyethylene in terms of the mechanical and structural properties. To quantify the degree of crosslinking, swelling studies were performed and from this it was observed that the crosslink density increased as the irradiation dose increased. Furthermore, a reduction was observed in the numerical data for molar mass between adjacent crosslinks and the number of monomeric units between adjacent crosslinks as the irradiation dose was conducted incrementally. Accelerated aging provided evidence that radicals became trapped in the polymer matrix of LDPE and this in turn initiated further reactions to transpire as time elapsed, leading to additional alteration in the structural properties. Fourier transform infrared spectroscopy (FTIR) was implemented to provide insight into this. This technique established that the aging process had increased the oxidative degradation products due to oxygen permeation into the polymer and double bonds within the material. Mechanical testing revealed an increase in the tensile strength and a decrease in the elongation at break. Accelerated aging caused additional modifications to occur in the mechanical properties which are further elucidated throughout this study. Dynamic frequency sweeps investigated the effects of irradiation on the structural properties of LDPE. The effect of varying the irradiation dose concentration was apparent as this controlled the level of crosslinking within the material. Maxwell and Kelvin or Voigt models were employed in this analytical technique to define the reaction procedure of the frequency sweep test with regards to non-crosslinked and crosslinked LDPE. (c) 2013 Elsevier B.V. All rights reserved.