Synthesis of magnetic nanoparticles of Fe3O4 and CoFe2O4 and their surface modification by surfactant adsorption

被引:0
|
作者
Zhao, SY
Lee, DK
Kim, CW
Cha, RG
Kim, YH
Kang, YS [1 ]
机构
[1] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea
[2] Shandong Univ, Dept Chem, Jinan 250100, Peoples R China
关键词
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fe3O4 and CoFe2O4 magnetic nanoparticles have been synthesized successfully in aqueous Solution and coated with oleic acid. The solid and organic solution of the synthesized nanoparticles was obtained. Self-assembled monolayer films were formed using organic solution of these nanoparticles. The crystal sizes determined by Debye-Scherre equation with XRD data were found close to the particle sizes calculated from TEM images, and this indicates that the synthesized particles are nanocrystalline. Especially, EDS, ED, FT-IR, TGA/DTA and DSC were used to characterize the nanoparticles and the oleic acid adsorption, and it was found that oleic acid molecule oil the Fe3O4 nanoparticle is a bilayer adsorption, while that oil CoFe2O4 nanoparticle is single layer adsorption. The superparamagnetic behavior of the nanoparticles was documented by the hysteresis loop measured at 300 K.
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页码:237 / 242
页数:6
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