Novel cleavage of (E)-allyl vic-diols to aldehydes using the 2nd-generation Grubbs catalyst

被引：21

作者：

Han, Chunguang ^{[1
]}

Uemura, Daisuke ^{[1
,2
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Keio Univ, Fac Sci & Technol, Dept Biosci & Informat, Yokohama, Kanagawa 2238522, Japan

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 49期

关键词：

(E)-allyl vic-diol; Cleavage; 2nd-Generation Grubbs catalyst; Alkyl vic-diol;

D O I：

10.1016/j.tetlet.2008.09.118

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Secondary (E)-allyl vic-diol cleavage in the presence of the 2nd-generation Grubbs catalyst has been developed. The position of a vic-diol adjacent to C=C plays a crucial role in the cleavage reaction compared to an alkyl vic-diol based on a model compound. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：6988 / 6990

页数：3

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