Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation

被引：4

作者：

Ogiwara, Yohei ^{[1
]}

Ono, Yuji ^{[1
]}

Sakai, Norio ^{[1
]}

机构：

[1] Tokyo Univ Sci RIKADAI, Fac Sci & Technol, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan

来源：

SYNTHESIS-STUTTGART | 2016年 / 48卷 / 23期

关键词：

indium catalyst; Oppenauer oxidation; primary alcohol; secondary alcohol; aldehyde; ketone; room temperature; AROMATIC-ALDEHYDES; ALUMINUM; REDUCTION; COMPLEXES; ALKOXIDES; LIGANDS;

D O I：

10.1055/s-0035-1562542

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indium(III) isopropoxide [In(Oi-Pr)(3)] was applicable as an Oppenauer oxidation catalyst, and the conversion of primary or secondary alcohols into the corresponding aldehydes or ketones was promoted at room temperature using pivalaldehyde as an oxidant.

引用

页码：4143 / 4148

页数：6

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