A neutral low-coordinate heterocyclic bismuth-tin species

被引：12
作者：
Hering-Junghans, C. [1 ]
Schulz, A. [1 ,2 ]
Villinger, A. [1 ]
机构：
[1] Univ Rostock, Inst Chem, D-18059 Rostock, Germany
[2] Univ Rostock, Leibniz Inst Katalyse eV, Abt Mat Design, D-18059 Rostock, Germany
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 72期
关键词：
STRUCTURAL-CHARACTERIZATION; DOUBLE-BOND; AR-NUMBER; COMPLEXES; ACTIVATION; OXIDATION; GE; CHEMISTRY; DIGERMYNE; LIGANDS;
D O I：
10.1039/c5cc04516a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of distannadiazane bearing bulky Ar-R*-groups (Ar-R* = C6H2{C(H)Ph-2}(2)R-2,6,4; R = iPr, tBu) with ECl3 (E = Sb, Bi) was studied resulting in the isolation of previously unknown N, N-bis(dichloropnictino) amines (3) and a novel heterocyclic carbenoid bismuth species (4) bearing a Bi-(III) and a Sn-(IV) center. The structure and bonding was investigated by means of X-ray structure elucidations and DFT calculations.
引用
收藏
页码：13834 / 13837
页数：4
相关论文
共 51 条
[41]   Synthesis of sterically encumbered 2,4-bis-m-terphenyl-1,3-dichloro-2,4-cyclo-dipnictadiazanes [m-TerNPnCl]2, (Pn = P, As) [J].
Reiss, Fabian ;
Schulz, Axel ;
Villinger, Alexander ;
Weding, Nico .
DALTON TRANSACTIONS, 2010, 39 (41) :9962-9972
[42]  
ROMANENKO VD, 1991, ZH OBSHCH KHIM+, V61, P2434
[43]   π-complexation of post-transition metals by neutral aromatic hydrocarbons:: The road from observations in the 19th century to new aspects of supramolecular chemistry [J].
Schmidbaur, Hubert ;
Schier, Annette .
ORGANOMETALLICS, 2008, 27 (11) :2361-2395
[44]   Cyclic Arsenic-Nitrogen Cations [J].
Schulz, Axel ;
Villinger, Alexander .
INORGANIC CHEMISTRY, 2009, 48 (15) :7359-7367
[45]   Low-Coordinate Bismuth Cations [J].
Schwamm, Ryan J. ;
Day, Benjamin M. ;
Coles, Martyn P. ;
Fitchett, Christopher M. .
INORGANIC CHEMISTRY, 2014, 53 (07) :3778-3787
[46]  
Smith P.J., 1978, ANNREVNMR SPEC, V8, P291
[47]   CYCLIC BIS(AMINO)-ARSACHLORIDE, BIS(AMINO)-STIBACHLORIDE, BIS(AMINO)-BISMACHLORIDE AND A SPECIAL TRIS(AMINO)BISMUTANE [J].
VEITH, M ;
BERTSCH, B .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 557 (02) :7-22
[48]   CYCLIC NITROGEN DERIVATIVES OF TETRA- AND DIVALENT TIN [J].
VEITH, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (04) :263-264
[49]   THE ELEMENT-NITROGEN DOUBLE-BOND IN CATIONS OF CYCLIC BIS(AMINO)PHOSPHAMUTHINES, BIS(AMINO)-ARSAMUTHINES, BIS(AMINO)-STIBAMUTHINES, AND BISMUTHINES [J].
VEITH, M ;
BERTSCH, B ;
HUCH, V .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 559 (04) :73-88
[50]  
Veith M., 1975, Angew. Chem, V87, P287
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