A neutral low-coordinate heterocyclic bismuth-tin species

被引：12

作者：

Hering-Junghans, C. ^{[1
]}

Schulz, A. ^{[1
,2
]}

Villinger, A. ^{[1
]}

机构：

[1] Univ Rostock, Inst Chem, D-18059 Rostock, Germany

[2] Univ Rostock, Leibniz Inst Katalyse eV, Abt Mat Design, D-18059 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 72期

关键词：

STRUCTURAL-CHARACTERIZATION; DOUBLE-BOND; AR-NUMBER; COMPLEXES; ACTIVATION; OXIDATION; GE; CHEMISTRY; DIGERMYNE; LIGANDS;

D O I：

10.1039/c5cc04516a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of distannadiazane bearing bulky Ar-R*-groups (Ar-R* = C6H2{C(H)Ph-2}(2)R-2,6,4; R = iPr, tBu) with ECl3 (E = Sb, Bi) was studied resulting in the isolation of previously unknown N, N-bis(dichloropnictino) amines (3) and a novel heterocyclic carbenoid bismuth species (4) bearing a Bi-(III) and a Sn-(IV) center. The structure and bonding was investigated by means of X-ray structure elucidations and DFT calculations.

引用

页码：13834 / 13837

页数：4

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