Paradoxes of the Standard Adiabatic Born-Oppenheimer Approach to Collision Processes. Their Origin and Possible Solutions

被引：0

作者：

Belyaev, A. K. ^{[1
]}

机构：

[1] Herzen Univ, Dept Theoret Phys, St Petersburg 191186, Russia

来源：

XXVII INTERNATIONAL CONFERENCE ON PHOTONIC, ELECTRONIC AND ATOMIC COLLISIONS (ICPEAC 2011), PTS 1-15 | 2012年 / 388卷

关键词：

ATOMIC-COLLISIONS;

D O I：

10.1088/1742-6596/388/9/092005

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

It is demonstrated that conventional applications of the standard adiabatic Born-Oppenheimer approach lead to paradoxes such as nonzero inelastic cross sections for noninteracting collision systems and infinite inelastic collision cross sections. The origin of these paradoxes is the molecular state problem. The quantum solution of the problem, the multielectron reprojection method, is proposed within the standard BO approach.

引用

页数：1

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