Rate-acceleration of TEMPO-mediated Polymerization of Styrene in the Presence of Various Acids

被引：1

作者：

Hong, Chang Kook ^{[2
]}

Jang, Heang Sin ^{[1
]}

Hong, Sang Hyun ^{[1
]}

Shim, Sang Eun ^{[1
]}

机构：

[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea

[2] Chonnam Natl Univ, Sch Appl Chem Engn, Kwangju 500757, South Korea

来源：

MACROMOLECULAR RESEARCH | 2009年 / 17卷 / 01期

关键词：

living polymerization; TEMPO-mediated; polymerization rate; organic acid; rate-acceleration; FREE-RADICAL POLYMERIZATION; BLOCK-COPOLYMERS; RATE ENHANCEMENT; AGENTS;

D O I：

10.1007/BF03218595

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The acceleration effect of various organic acids, such as methanesulfonic acid (MSA), ethanesulfonic acid (ESA), 4,4'-sulfonyldibenzoic acid (SDA), diphenylacetic acid (DPAA), and rho-toluenesulfonic acid (TSA), on the rate of styrene bulk polymerization with 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) and benzoyl peroxide (BPO) was investigated. The addition of organic acids significantly accelerated the rate. Among these organic acids, DPAA showed an efficient rate-accelerating effect with living nature of polymerization. When DPAA was used as a rate-accelerating additive for TEMPO-mediated living free radical polymerization (LFRP), the rate of polymerization was dramatically enhanced, the linearity of reaction kinetics was successfully maintained, and the polydispersity was effectively controlled.

引用

页码：14 / 18

页数：5

共 50 条

[41] Oxygen permeability and biodegradability of polyuronic acids prepared from polysaccharides by TEMPO-mediated oxidation
Kato, Y
Kaminaga, J
Matsuo, R
Isogai, A
JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2005, 13 (03) : 261 - 266
[42] Oxygen Permeability and Biodegradability of Polyuronic Acids Prepared from Polysaccharides by TEMPO-Mediated Oxidation
Yumiko Kato
Jun-ichi Kaminaga
Rukichi Matsuo
Akira Isogai
Journal of Polymers and the Environment, 2005, 13 : 261 - 266
[43] Effect of synthesis conditions on the mechanism of reversible inhibition in the TEMPO-mediated polymerization of 4-vinylpyridine
M. Yu. Zaremskii
Sin Chen
A. P. Orlova
I. V. Blagodatskikh
Polymer Science Series B, 2013, 55 : 526 - 540
[44] Synthesis of end-functionalized polymer with cyclodextrin based on tempo-mediated radical polymerization.
Narumi, A
Miura, Y
Satoh, T
Kaga, H
Kakuchi, T
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U445 - U445
[45] Radical Polymerization of Styrene Mediated by Dinitrones of Various Structures
E. V. Kolyakina
A. B. Alyeva
E. V. Sazonova
E. A. Zakharychev
D. F. Grishin
Polymer Science, Series B, 2020, 62 : 328 - 342
[46] Radical Polymerization of Styrene Mediated by Dinitrones of Various Structures
Kolyakina, E. V.
Alyeva, A. B.
Sazonova, E. V.
Zakharychev, E. A.
Grishin, D. F.
POLYMER SCIENCE SERIES B, 2020, 62 (04) : 328 - 342
[47] Catalytic Oxidation of Alcohols to Corresponding Aldehydes or Ketones with TEMPO-Mediated Iodosobenzene in Water in the Presence of a Surfactant
Zhu, Chenjie
Wei, Yunyang
Ji, Lei
SYNTHETIC COMMUNICATIONS, 2010, 40 (14) : 2057 - 2066
[48] Heterophase polymerization of styrene in the presence of organosilicon compounds of various natures
I. A. Gritskova
V. S. Papkov
I. G. Krasheninnikova
A. M. Evtushenko
Polymer Science Series A, 2007, 49 : 235 - 241
[49] Effect of the addition of inert or TEMPO-capped prepolymer on polymerization rate and molecular weight development in the nitroxide-mediated radical polymerization of styrene
Roa-Luna, Martha
Nabifar, Afsaneh
McManus, Neil T.
Vivaldo-Lima, Eduardo
Lona, Liliane M. F.
Penlidis, Alexander
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 109 (06) : 3665 - 3678
[50] Heterophase polymerization of styrene in the presence of organosilicon compounds of various natures
Gritskova, I. A.
Papkov, V. S.
Krasheninnikova, I. G.
Evtushenko, A. M.
POLYMER SCIENCE SERIES A, 2007, 49 (03) : 235 - 241

← 1 2 3 4 5 →