Composite-Hydroxide-Assisted Hydrothermal Synthesis of Magnesium Silicate Nanotube

被引：3

作者：

Chen Lan-Hua ^{[1
]}

Li Xuan ^{[1
]}

Guo Xiang-Ke ^{[1
]}

Guo Xue-Feng ^{[1
]}

Ding Wei-Ping ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 07期

关键词：

nanotube; hydrothermal synthesis; magnesium silicate; composite-hydroxide; eutectic solution; HYDROSILICATES; CATALYST; LEAD;

D O I：

10.3969/j.issn.1001-4861.2013.00.277

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mild and highly efficient hydrothermal synthesis method for uniform magnesium silicate nanotubes was developed from normal Mg(OH)(2) and SiO2 powders with the assistance of potassium hydroxide and sodium hydroxide. The samples were characterized by XRD, TEM, IR, and nitrogen adsorption-desorption. The synthetic process was studied by XRD, TEM, etc. The results indicate that the eutectic solution of potassium hydroxide and sodium hydroxide offers higher dissolvability for the reactants and benefits the reaction between the reactants. This composite-hydroxide-assisted approach is a mild and highly efficient procedure for the synthesis of high quality magnesium silicate nanotubes at 250 degrees C in a short duration of 36 hours, while it needs over 7 days at 250 degrees C for traditional hydrothermal method.

引用

页码：1333 / 1338

页数：6

共 31 条

[11] Morphology Study of New Shaped Porous Nanotubes of LiFePO4 by Electrospinning
Kang, Chung Soo
Kim, Cheong
Park, Tae Jun
Son, Jong Tae
[J]. CHEMISTRY LETTERS, 2012, 41 (11) : 1428 - 1429
[12] Protonated Titanate Nanotubes as Solid Acid Catalyst
Kitano, Masaaki
Nakajima, Kiyotaka
Kondo, Junko N.
Hayashi, Shigenobu
Hara, Michikazu
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (19) : 6622 - +
[13] Hydrothermal synthesis of nanotubular Co-Mg hydrosilicates with the chrysotile structure
Korytkova, E. N.
Pivovarova, L. N.
Drosdova, I. A.
Gusarov, V. V.
[J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (10) : 1669 - 1676
[14] Synthesis of nanotubular nickel hydrosilicates and nickel-magnesium hydrosilicates under hydrothermal conditions
Korytkova, EN
Pivovarova, LN
Drozdova, IA
Gusarov, VV
[J]. GLASS PHYSICS AND CHEMISTRY, 2005, 31 (06) : 797 - 802
[15] Formation of Mg3Si2O5(OH)4 nanotubes under hydrothermal conditions
Korytkova, EN
Maslov, AV
Pivovarova, LN
Drozdova, IA
Gusarov, VV
[J]. GLASS PHYSICS AND CHEMISTRY, 2004, 30 (01) : 51 - 55
[16] Liu FL, 2012, CHINESE J INORG CHEM, V28, P861
[17] Composite-hydroxide-mediated approach for the synthesis of nanostructures of complex functional-oxides
Liu, Hong
Hu, Chenguo
Wang, Zhong Lin
[J]. NANO LETTERS, 2006, 6 (07) : 1535 - 1540
[18] Liu SQ, 2007, CHINESE J INORG CHEM, V23, P827
[19] Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles
Pan, Xiulian
Fan, Zhongli
Chen, Wei
Ding, Yunjie
Luo, Hongyuan
Bao, Xinhe
[J]. NATURE MATERIALS, 2007, 6 (07) : 507 - 511
[20] Metal silicate nanotubes with nanostructured walls as superb adsorbents for uranyl ions and lead ions in water
Qu, Jin
Li, Wei
Cao, Chang-Yan
Yin, Xiao-Jie
Zhao, Liang
Bai, Jing
Qin, Zhi
Song, Wei-Guo
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (33) : 17222 - 17226

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