Study on an integrated natural gas fuel processor for 2-kW solid oxide fuel cell

被引:7
作者
Ni, Changjun [1 ,2 ]
Yuan, Zhongshan [1 ]
Wang, Sheng [1 ]
Li, Deyi [1 ]
Zhang, Cheng [1 ]
Li, Jian [3 ]
Wang, Shudong [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Huazhong Univ Sci & Technol, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrogen production; Integrated fuel processor; Compact reformer; Methane; Steam reforming; SOFC; COMPACT STEAM REFORMER; PARTIAL OXIDATION; THERMODYNAMIC ANALYSIS; ENDOTHERMIC REACTIONS; CATALYTIC COMBUSTOR; HYDROGEN-PRODUCTION; HEAT-GENERATION; REACTOR; METHANE; PERFORMANCE;
D O I
10.1016/j.ijhydene.2015.09.067
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A natural gas fuel processor integrated a compact reformer with two heat exchangers was developed and tested as a hydrogen generator for 2 kW distributed solid oxide fuel cell (SOFC) applications. The compact reformer is comprised of a reforming chamber and two non-catalytic combustion chambers, in which the endothermic and exothermic reactions are coupled into a multilayered cylindrical reactor vessel. The integrated fuel processor can be started up quickly by the combustion of methane and run steadily within 30 min under the preferred thermodynamic operating conditions. The higher temperature zone is located at the latter half part of the reforming chamber, where the temperature gradient is relatively small and favorable for hydrogen production. The results show that a high methane conversion and H-2 molar fraction (dry basis) can be achieved, irrespective of the hydrogen production capacity. The energy efficiency of the integrated fuel processor can reach 74.11% when producing 2 Nm(3)/h of H-2. A SOFC system was fueled successfully by the generated hydrogen-rich reformate in the integrated fuel processor. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:15491 / 15502
页数:12
相关论文
共 47 条
[1]   Fuel cells and energy networks of electricity, heat, and hydrogen in residential areas [J].
Aki, Hirohisa ;
Yamamoto, Shigeo ;
Kondoh, Junji ;
Maeda, Tetsuhiko ;
Yamaguchi, Hiroshi ;
Murata, Akinobu ;
Ishii, Itaru .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (08) :967-980
[2]  
[Anonymous], 2004, Fuel Cell Handbook, V7
[3]   Modeling and parametric study of a 1 kWe HT-PEMFC-based residential micro-CHP system [J].
Arsalis, A. ;
Nielsen, Mads P. ;
Kaer, Soren K. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (08) :5010-5020
[4]   Influence of Operating Conditions on Carbon Deposition Over a Ni Catalyst for the Production of Synthetic Natural Gas (SNG) from Coal [J].
Bai, Xiaobo ;
Wang, Sheng ;
Sun, Tianjun ;
Wang, Shudong .
CATALYSIS LETTERS, 2014, 144 (12) :2157-2166
[5]   A comparative study of two different configurations for exothermic-endothermic heat exchanger reactor [J].
Bayat, M. ;
Rahimpour, M. R. ;
Taheri, M. ;
Pashaei, M. ;
Sharifzadeh, S. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2012, 52 :63-73
[6]   Small stationary reformers for H2 production from hydrocarbons [J].
Calo, Eugenio ;
Giannini, Antonella ;
Monteleone, Giulia .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (18) :9828-9835
[7]   Thermodynamic analysis of natural-gas fuel processing for fuel cell applications [J].
Chan, SH ;
Wang, HM .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2000, 25 (05) :441-449
[8]   Performance of a 5 kWe fuel processor for polymer electrolyte fuel cells [J].
Cipiti, F. ;
Pino, L. ;
Vita, A. ;
Lagana, M. ;
Recupero, V. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (12) :3197-3203
[9]   Process intensification using multifunctional reactors [J].
Dautzenberg, FM ;
Mukherjee, M .
CHEMICAL ENGINEERING SCIENCE, 2001, 56 (02) :251-267
[10]   A new reactor concept for endothermic high-temperature reactions [J].
Frauhammer, J ;
Eigenberger, G ;
von Hippel, L ;
Arntz, D .
CHEMICAL ENGINEERING SCIENCE, 1999, 54 (15-16) :3661-3670