Amide-bridged ladder poly(p-phenylene): synthesis by direct arylation and π-stacked assembly

被引：11
作者：
Takagi, K. [1 ]
Kato, R. [1 ]
Yamamoto, S. [1 ]
Masu, H. [2 ]
机构：
[1] Nagoya Inst Technol, Dept Mat Sci & Engn, Nagoya, Aichi 4668555, Japan
[2] Chiba Univ, Ctr Analyt Instrumentat, Chiba, Chiba 2638522, Japan
来源：
POLYMER CHEMISTRY | 2015年 / 6卷 / 38期
关键词：
EFFICIENT SYNTHESIS; OPTICAL-PROPERTIES; POLYMERS; ARENES; OLIGOTHIOPHENE; CHROMOPHORES; DERIVATIVES; CYCLIZATION; OLIGOMERS;
D O I：
10.1039/c5py01154j
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Amide-bridged ladder poly(p-phenylene) was synthesized in two steps, through the polycondensation of aromatic diamines and dicarboxylic acid derivatives followed by palladium-catalyzed intramolecular direct arylation. The pi-stacked assembly of the polymer in solution was investigated along with the single crystal X-ray structure analysis of a model oligomer.
引用
收藏
页码：6792 / 6795
页数：4
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