Direct catalytic oxidation of methane to methanol over zeolite encapsulated transition metal complexes

被引：0

作者：

Varkey, SP ^{[1
]}

Jacob, CR

机构：

[1] Ben Gurion Univ Negev, Blechner Ctr Ind Catalysis & Proc Dev, IL-84105 Beer Sheva, Israel

[2] Natl Chem Lab, Poona 411008, Maharashtra, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1999年 / 38卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zeolite encapsulated metal complexes ML (M=Cu or Mn; L=salen or substituted salens or octaaza macrocyclic ligand) have been synthesized and their catalytic activities studied for the selective aerobic oxidation of methane at 273 K using TBHP as a promoter and acetonitrile or water as solvent. The zeolite encapsulated macrocyclic complex is found to be a better catalyst for the oxidation of methane with respect to conversion and selectivity towards methanol. Acetonitrile seems to be a good solvent for this reaction. Catalyst could be recycled and reused.

引用

页码：320 / 324

页数：5

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