High pressure, high temperature electrochemical synthesis of metal-organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies

被引：174
作者：
Campagnol, Nicolo [1 ]
Van Assche, Tom [2 ]
Boudewijns, Tom [3 ]
Denayer, Joeri [2 ]
Binnemans, Koen [4 ]
De Vos, Dirk [3 ]
Fransaer, Jan [1 ]
机构：
[1] KU Leuven Univ Leuven, Dept Met & Mat Engn MTM, B-3001 Louvain, Belgium
[2] Vrije Univ Brussel, Dept Chem Engn, B-1050 Brussels, Belgium
[3] KU Leuven Univ Leuven, Ctr Surface Chem & Catalysis COK, B-3001 Louvain, Belgium
[4] KU Leuven Univ Leuven, Dept Chem, B-3001 Louvain, Belgium
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 19期
关键词：
ADSORPTION;
D O I：
10.1039/c3ta10419b
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Thanks to a new high temperature electrodeposition setup, MIL-100(Fe) is synthesized and deposited electrochemically for the first time. In comparison to other methods commonly used to produce this MOF, the reported synthesis allows formation of layers, and it takes place under milder conditions. The layers have been tested for anti-fouling, gas adsorption and vapor separation. With the same setup Cu-BTC MOF HKUST-1 has been deposited at different temperatures obtaining different morphologies.
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收藏
页码：5827 / 5830
页数：4
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