Observation of dihydrated glycine

被引：23

作者：

Alonso, Jose L. ^{[1
]}

Pena, Isabel ^{[1
]}

Eugenia Sanz, M. ^{[1
]}

Vaquero, Vanesa ^{[1
]}

Mata, Santiago ^{[1
]}

Cabezas, Carlos ^{[1
]}

Lopez, Juan C. ^{[1
]}

机构：

[1] Univ Valladolid, GEM, Labs Espect & Bioespect, Area Quim Fis, E-47005 Valladolid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 33期

关键词：

MILLIMETER WAVE SPECTRUM; CONFORMERS; MICROSOLVATION; RELAXATION;

D O I：

10.1039/c3cc40344k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex of glycine with two water molecules glycine-(H2O)(2) has been generated by laser ablation in a supersonic expansion and characterised using rotational spectroscopy. The water molecules bind to the carboxylic group of glycine and to each other through three intermolecular hydrogen bonds, closing an eight-membered ring. In the complex, glycine adopts the conformation found to be the most stable for bare glycine.

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收藏

页码：3443 / 3445

页数：3

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