Editors' Choice-Review-Conductive Forms of MoS2 and Their Applications in Energy Storage and Conversion

被引:74
作者
Saha, Dipankar [1 ]
Kruse, Peter [1 ]
机构
[1] McMaster Univ, Dept Chem & Chem Biol, Hamilton, ON L8S 4M1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Electrocatalysis; Dichalcogenide; Energy Conversion; Energy Storage; Graphene; Surface modification; HYDROGEN EVOLUTION REACTION; TRANSITION-METAL DICHALCOGENIDES; CHEMICALLY EXFOLIATED MOS2; HIGH-YIELD PREPARATION; SINGLE-LAYER MOS2; MOLYBDENUM-DISULFIDE; MONOLAYER MOS2; ELECTROCATALYTIC ACTIVITY; LITHIUM INTERCALATION; EFFICIENT CATALYST;
D O I
10.1149/1945-7111/abb34b
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Conductive forms of MoS(2)are important emerging 2D materials due to their unique combination of properties such as high electrical conductivity, availability of active sites in edge and basal planes for catalytic activity and expanded interlayer distances. Consequently, there has been a drive to find synthetic routes toward conductive forms of MoS2. Naturally occurring or synthetically grown semiconducting 2H-MoS(2)can either be converted into metallic 1T-MoS2, or various dopants may be introduced to modulate the electronic band gap of the 2H-MoS(2)phase and increase its conductivity. Chemical and electrochemical intercalation methods, hydrothermal and solvothermal processes, and chemical vapor deposition have all been developed to synthesize conductive MoS2. Conductive MoS(2)finds applications in energy storage devices, electrocatalytic reactions, and sensors. Here, we summarize a detailed understanding of the atomic structure and electronic properties of conductive MoS(2)which is crucial for its applications. We also discuss various fabrication methods that have been previously reported along with their advantages and disadvantages. Finally, we will give an overview of current trends in different applications in energy storage and electrocatalytic reactions in order to help researchers to further explore the applications of conductive MoS2.
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页数:18
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共 198 条
[1]  
Acerce M, 2015, NAT NANOTECHNOL, V10, P313, DOI [10.1038/nnano.2015.40, 10.1038/NNANO.2015.40]
[2]   The influence of precursor on rhenium incorporation into Re-doped MoS2 (Mo1-xRexS2) thin films by aerosol-assisted chemical vapour deposition (AACVD) [J].
Al-Dulaimi, Naktal ;
Lewis, Edward A. ;
Savjani, Nicky ;
McNaughter, Paul D. ;
Haigh, Sarah J. ;
Malik, M. Azad ;
Lewis, David J. ;
O'Brien, Paul .
JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (35) :9044-9052
[3]   Robust carbon dioxide reduction on molybdenum disulphide edges [J].
Asadi, Mohammad ;
Kumar, Bijandra ;
Behranginia, Amirhossein ;
Rosen, Brian A. ;
Baskin, Artem ;
Repnin, Nikita ;
Pisasale, Davide ;
Phillips, Patrick ;
Zhu, Wei ;
Haasch, Richard ;
Klie, Robert F. ;
Kral, Petr ;
Abiade, Jeremiah ;
Salehi-Khojin, Amin .
NATURE COMMUNICATIONS, 2014, 5
[4]   Stable, Single-Layer MX2 Transition-Metal Oxides and Dichalcogenides in a Honeycomb-Like Structure [J].
Ataca, C. ;
Sahin, H. ;
Ciraci, S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (16) :8983-8999
[5]   A Comparative Study of Lattice Dynamics of Three- and Two-Dimensional MoS2 [J].
Ataca, C. ;
Topsakal, M. ;
Akturk, E. ;
Ciraci, S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (33) :16354-16361
[6]   Effect of Intercalated Metals on the Electrocatalytic Activity of 1T-MoS2 for the Hydrogen Evolution Reaction [J].
Attanayake, Nuwan H. ;
Thenuwara, Akila C. ;
Patra, Abhirup ;
Aulin, Yaroslav V. ;
Tran, Thi M. ;
Chakraborty, Himanshu ;
Borguet, Eric ;
Klein, Michael L. ;
Perdew, John P. ;
Strongin, Daniel R. .
ACS ENERGY LETTERS, 2018, 3 (01) :7-13
[7]   Covalent Nitrogen Doping and Compressive Strain in MoS2 by Remote N2 Plasma Exposure [J].
Azcatl, Angelica ;
Qin, Xiaoye ;
Prakash, Abhijith ;
Zhang, Chenxi ;
Cheng, Lanxia ;
Wang, Qingxiao ;
Lu, Ning ;
Kim, Moon J. ;
Kim, Jiyoung ;
Cho, Kyeongjae ;
Addou, Rafik ;
Hinkle, Christopher L. ;
Appenzeller, Joerg ;
Wallace, Robert M. .
NANO LETTERS, 2016, 16 (09) :5437-5443
[8]   Solid-State Chemiresistors from Two-Dimensional MoS2 Nanosheets Functionalized with L-Cysteine for In-Line Sensing of Part-Per-Billion Cd2+ Ions in Drinking Water [J].
Bazylewski, Paul ;
Van Middelkoop, Sheldon ;
Divigalpitiya, Ranjith ;
Fanchini, Giovanni .
ACS OMEGA, 2020, 5 (01) :643-649
[9]   Carbons and Electrolytes for Advanced Supercapacitors [J].
Beguin, Francois ;
Presser, Volker ;
Balducci, Andrea ;
Frackowiak, Elzbieta .
ADVANCED MATERIALS, 2014, 26 (14) :2219-2251
[10]   Balancing the Hydrogen Evolution Reaction, Surface Energetics, and Stability of Metallic MoS2 Nanosheets via Covalent Functionalization [J].
Benson, Eric E. ;
Zhang, Hanyu ;
Schuman, Samuel A. ;
Nanayakkara, Sanjini U. ;
Bronstein, Noah D. ;
Ferrere, Suzanne ;
Blackburn, Jeffrey L. ;
Miller, Elisa M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (01) :441-450