Factors that determine thione( thiol)- disulfide interconversion in a bis( thiosemicarbazone) copper( II) complex

被引：9

作者：

Jeong, Haewon ^{[1
]}

Kang, Yeji ^{[1
]}

Kim, Jin ^{[2
]}

Kim, Byung-Kwon ^{[1
]}

Hong, Seungwoo ^{[1
]}

机构：

[1] Sookmyung Womens Univ, Dept Chem, Seoul 04310, South Korea

[2] Korea Basic Sci Inst, Western Seoul Ctr, Seoul 03759, South Korea

来源：

RSC ADVANCES | 2019年 / 9卷 / 16期

关键词：

DYNAMIC COMBINATORIAL CHEMISTRY; CHELATING-AGENTS; GLUTATHIONE; ELECTROCHEMISTRY; PENICILLAMINE; LIBRARIES; OXIDATION; DNA;

D O I：

10.1039/c9ra01115c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.

引用

页码：9049 / 9052

页数：4