Factors that determine thione( thiol)- disulfide interconversion in a bis( thiosemicarbazone) copper( II) complex

被引：8
作者：
Jeong, Haewon [1 ]
Kang, Yeji [1 ]
Kim, Jin [2 ]
Kim, Byung-Kwon [1 ]
Hong, Seungwoo [1 ]
机构：
[1] Sookmyung Womens Univ, Dept Chem, Seoul 04310, South Korea
[2] Korea Basic Sci Inst, Western Seoul Ctr, Seoul 03759, South Korea
来源：
RSC ADVANCES | 2019年 / 9卷 / 16期
关键词：
DYNAMIC COMBINATORIAL CHEMISTRY; CHELATING-AGENTS; GLUTATHIONE; ELECTROCHEMISTRY; PENICILLAMINE; LIBRARIES; OXIDATION; DNA;
D O I：
10.1039/c9ra01115c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.
引用
收藏
页码：9049 / 9052
页数：4
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