Gap-filling of Cu-Al alloy into nanotrenches by cyclic metalorganic chemical vapor deposition

被引:2
作者
Moon, H. K. [1 ]
Lee, S. J. [1 ]
Yoon, J. [2 ]
Kim, H. [2 ]
Lee, N. -E. [1 ,3 ]
机构
[1] Sungkyunkwan Univ SKKU, Sch Adv Mat Sci & Engn, Ctr Adv Plasma Surface Technol, Suwon 440746, Gyeonggi Do, South Korea
[2] Yonsei Univ, Sch Elect & Elect Engn, Seoul 120749, South Korea
[3] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol SAINT, Suwon 440746, Gyeonggi Do, South Korea
关键词
Alloys; Thin films; Vapor deposition; Electron microscopy; Microstructure; THIN-FILMS; COPPER; ROUTE;
D O I
10.1016/j.materresbull.2012.04.107
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, Cu-Al alloy thin films with lower values of electrical resistivity than that of an Al-free Cu thin film were produced by cyclic metalorganic chemical vapor deposition (MOCVD), followed by thermal annealing of the Cu/Al multilayer formed, with controlled Cu and Al precursor delivery times. The Ru-coated SiO2 trench with the opening width of 50 nm and aspect ratio of 1:6.7 could be completely filled by the Cu-Al alloy. The Ru/SiO2 trench, filled conformally and voidlessly by the Cu-Al (0.7 at.%) alloy, showed no presence of intermetallic compounds. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2961 / 2965
页数:5
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