Preparation and Properties of C=X (X: O, N, S) Based Distillable Ionic Liquids and Their Application for Rare Earth Separation

被引：24

作者：

Li, Guofeng ^{[1
]}

Xue, Zhimin ^{[2
]}

Cao, Bobo ^{[3
]}

Yan, Chuanyu ^{[1
]}

Mu, Tiancheng ^{[1
]}

机构：

[1] Renmin Univ China, Dept Chem, 59 Zhongguanchun St, Beijing 100872, Peoples R China

[2] Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, 35 Qinghuadong Rd, Beijing 100083, Peoples R China

[3] Qufu Normal Univ, Sch Chem & Chem Engn, 57 Jingxuanxi Rd, Qufu 273165, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2016年 / 4卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Distillable ionic liquids; Rare earth separation; Physicochemical properties; DECOMPOSITION MECHANISMS; THERMAL-DECOMPOSITION; SOLVENT; STABILITIES; EXTRACTION; CONVERSION; CHEMISTRY; PHASE;

D O I：

10.1021/acssuschemeng.6b01984

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The negligible vapor pressure of ionic liquids prevents the separation of ionic liquids from other nonvolatile substances by distillation. Most distillable ionic liquids have been reported are protic ionic liquids, and the aprotic ionic liquids are still scarce. In this work, we designed and synthesized a series of unsaturated bond (C=X; X is O, N, S) based ionic liquids and some of them could be distilled at a mild condition. Moreover, [MDMF]TfO shows a high efficiency for separation of EuCl3 from the mixture of EuCl3 and NdCl3.

引用

页码：6258 / 6262

页数：5

共 35 条

[21] 2,3-diferrocenyl-(1-triphenylphosphoranylidene)ketene: Synthesis and interactions with O, C, N, S, Se nucleophiles, characterization and X-ray diffraction [J].

Oliva-Colunga, Claudia O. ;

Garcia, Jessica J. Sanchez ;

Aguilar-Ortiz, Edgar A. ;

Flores-Alamo, Marcos ;

Ruiz-Azuara, Lena ;

Klimova, Elena I. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2025, 1024

[22] Design, preparation and properties of high-performance Z-scheme Bi2MoO6/g-C3N4-x composite photocatalyst [J].

Zhou, Boxun ;

Liu, Qi ;

Zhang, Shici ;

Sanjrani, Manzoor ;

Yang, Hang ;

Xia, Shibin .

CHEMICAL PHYSICS LETTERS, 2020, 748

[23] Organophosphorus ligands with XPNSO skeleton (X = O, S) and their Pd(II) complexes. Crystal and molecular structure of [{XP(OEt)2}(O2SR)]NH (X = O, R = Me, Ph; X = S, R = C6H4Cl-4) and Pd[{SP(OEt)2}(O2SC6H4Cl-4)N]2 [J].

Oltean, Dorel ;

Poellnitz, Alpar ;

Silvestru, Anca .

POLYHEDRON, 2013, 53 :67-75

[24] Evaluation of separation properties of a modified strong cation exchange material named MEX and its application in 2D-MEX x C18 system to separate peptides from scorpion venom [J].

Chen, Bo ;

Xu, Junyan ;

Fu, Qing ;

Dong, Xuefang ;

Guo, Zhimou ;

Jin, Yu ;

Liang, Xinmiao .

ANALYST, 2015, 140 (13) :4676-4686

[25] N, S co-doped graphene quantum dots promote charge separation of Bi4O5BrxI2_x solid solution and enhance visible light photocatalytic performance [J].

Gao, Xiaoming ;

Li, QianGen ;

Zhu, Wei ;

Li, Xibao ;

Guo, Yanhong .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2022, 648

[26] Molecular engineering of the electronic, structural, and electrochemical properties of nanostructured 1-methyl-4-phenyl 1,2,4 triazolium-based [PhMTZ][X1-10] ionic liquids through anionic changing [J].

Roohi, Hossein ;

Salehi, Roya .

IONICS, 2018, 24 (02) :483-504

[27] Ionic-Liquid-Assisted Synthesis of N, F, and B Co-Doped CoFe2O4-x on Multiwalled Carbon Nanotubes with Enriched Oxygen Vacancies for Li-S Batteries [J].

Hu, Shunyou ;

Yi, Mingjie ;

Wu, Hao ;

Wang, Tiansheng ;

Ma, Xing ;

Liu, Xiangli ;

Zhang, Jiaheng .

ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (14)

[28] Size- and dimensionality-dependent optical, magnetic and magneto-optical properties of binary europium-based nanocrystals: EuX (X = O, S, Se, Te) [J].

Zhou, Xingzhi ;

Zhang, Kelvin H. L. ;

Xiong, Jie ;

Park, Ju-Hyun ;

Dickerson, James H. ;

He, Weidong .

NANOTECHNOLOGY, 2016, 27 (19)

[29] Phosphoryl Podands Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (Ln, n=0-5): Complexation and Extraction of Rare Earth Elements. Crystal Structures of [Ln2L03(NO3)6] • xH2O (Ln = Nd, x=1.99; Ln = Eu, x=1; Ln = Er, x=6.5; Ln = Lu, x=6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er) [J].

Polyakova, I. N. ;

Krivorot'ko, E. S. ;

Ivanova, I. S. ;

Pyatova, E. N. ;

Demin, S. V. ;

Zhilov, V. I. ;

Baulin, V. E. ;

Ilyukhin, A. B. ;

Tsivadze, A. Yu. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (10) :1372-1380

[30] Phosphoryl Podands Ph2P(O)CH2O(CH2CH2O)nCH2P(O)Ph2 (Ln, n = 0–5): Complexation and Extraction of Rare Earth Elements. Crystal Structures of [Ln2L03(NO3)6] · xH2O (Ln = Nd, x = 1.99; Ln = Eu, x = 1; Ln = Er, x = 6.5; Ln = Lu, x = 6) and [LnL2(NO3)3(H2O)] (Ln = Nd, Er) [J].

I. N. Polyakova ;

E. S. Krivorot’ko ;

I. S. Ivanova ;

E. N. Pyatova ;

S. V. Demin ;

V. I. Zhilov ;

V. E. Baulin ;

A. B. Ilyukhin ;

A. Yu. Tsivadze .

Russian Journal of Inorganic Chemistry, 2018, 63 :1372-1380

← 1 2 3 4 →