Synthesis and Hydrogen-bonded Interpenetrating Grid Structure of 5,5′-Bis[4-(2-hydroxyethyl)phenyl]diazo-dipyrromethane

被引：0

作者：

Li Can ^{[1
]}

Li Bo-Yang ^{[1
]}

Sun Shi-Peng ^{[1
]}

Yin Zhen-Ming ^{[1
]}

机构：

[1] Tianjin Normal Uinvers, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2012年 / 31卷 / 06期

基金：

中国国家自然科学基金;

关键词：

5,5 '-bisdiazo-dipyrromethane; hydrogen bonds; interpenetrating; HETEROJUNCTION SOLAR-CELLS; BF2-AZOPYRROLE COMPLEX; SELF-ASSEMBLIES; AZO DYES; NETWORKS; DERIVATIVES; PATTERNS; DATABASE; DIMER;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 5,5'-bisdiazo-dipyrromethane compound 3 has been synthesized and characterized. The crystal of 3 is of orthorhombic, space group Iba2 with a = 19.1914(17), b = 9.8396(8), c = 13.7643(12) angstrom, V = 2599.2(4) angstrom(3), Z = 4, C29H34N6O2, M-r = 498.62, D-c = 1.274 g/cm(3), F(000) = 1064, mu(MoK alpha) = 0.083 mm(-1), the final R = 0.0302 and wR = 0.0786 for 6361 observed reflections with I > 2 sigma(1), and R = 0.0320 and wR = 0.08006 for all data. It reveals that the molecules of compound 3 assemble into grid structures through a R-2(2)(7) type hydrogen bonding motif between azopyrrole and hydroxyl group. The grids interpenetrate each other with the assistance of C-H center dot center dot center dot pi interaction.

引用

页码：797 / 802

页数：6

共 38 条

[1] Interpenetrated three-dimensional networks of hydrogen-bonded organic species: A systematic analysis of the Cambridge Structural Database [J].