Catalytic [3+2] annulation of ketimines with alkynes via C-H activation by a cationic iridium(cod) complex

被引：65

作者：

Nagamoto, Midori ^{[1
]}

Nishimura, Takahiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 47期

关键词：

N-SULFONYL KETIMINES; BOND ACTIVATION; ORGANIC-SYNTHESIS; INTERNAL ALKYNES; AROMATIC KETIMINES; INDENE FRAMEWORKS; ATOM ECONOMY; FUNCTIONALIZATION; CYCLIZATION; KETONES;

D O I：

10.1039/c4cc01874e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[3 + 2] Annulation of ketimines with internal and terminal alkynes proceeded via C-H activation to give aminoindene derivatives in high yields, which is catalyzed by a cationic iridium complex coordinated with 1,5-cyclooctadiene (cod).

引用

页码：6274 / 6277

页数：4

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