Disentanglement of Donation and Back-Donation Effects on Experimental Observables: A Case Study of Gold-Ethyne Complexes

被引：56
作者：
Bistoni, Giovanni [1 ,2 ]
Belpassi, Leonardo [1 ]
Tarantelli, Francesco [1 ,2 ]
机构：
[1] CNR, ISTM, I-06123 Perugia, Italy
[2] CNR, Dipartimento Chim Biol & Biotecnol, I-06123 Perugia, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 44期
关键词：
alkyne ligands; bond theory; density functional calculations; gold; multiple bonds; CARBENE; CATALYSIS; MODEL;
D O I：
10.1002/anie.201305505
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A charge-displacement analysis of gold-ethyne complexes shows the existence of a quantitative relationship between measurable properties and the chemical bond constituents in the Dewar-Chatt-Duncanson model. Through suitable experiments, these constituents may be disentangled and crucial insight into the nature of coordination bonds may thus be gained. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11599 / 11602
页数：4
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