Advances in the Enantioselective Metal-catalyzed N-H and O-H Insertion Reactions with Diazocarbonyl Compounds

被引：26

作者：

Burtoloso, Antonio C. B. ^{[1
]}

Santiago, Joao V. ^{[1
]}

Bernardim, Barbara ^{[1
]}

Talero, Alexander G. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil

来源：

CURRENT ORGANIC SYNTHESIS | 2015年 / 12卷 / 05期

基金：

巴西圣保罗研究基金会;

关键词：

Asymmetric catalysis; carbenes; diazocarbonyls; enantioselective; insertion reactions; metal catalysis; DIAZO-COMPOUNDS; DIRHODIUM(II) CARBOXYLATES; ASYMMETRIC-SYNTHESIS; 3-COMPONENT REACTION; CARBENOID INSERTION; EFFICIENT APPROACH; BONDS; DIAZOACETATES; RHODIUM; DIAZOKETONES;

D O I：

10.2174/157017941205150821153658

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Insertion of diazocarbonyl-derived metallocarbenes into X-H bonds (X= H, C, Si, N, O, S, P, Se) has proven to be a very important method for the construction of C-X bonds in organic chemistry. This mini-review provides a brief historical background, mechanistic aspects and a summary of recent breakthroughs in the area of enantioselective metal-catalyzed N-H and O-H insertion reactions.

引用

页码：650 / 659

页数：10

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