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Enhanced visible light photocatalytic activity of Cl-Bi2WO6/g-C3N4 composite photocatalyst
被引:9
作者:
Gao, Yanhua
[1
]
Yang, Wei
[1
]
Shan, Xinyao
[1
]
Chen, Ying
[1
]
机构:
[1] Northeast Petr Univ, Coll Chem & Chem Engn, Daqing 163318, Heilongjiang, Peoples R China
关键词:
Cl-Bi2WO6/g-C3N4;
electrostatic adsorption;
g-C3N4;
heterogeneous junction;
GRAPHITIC CARBON NITRIDE;
QUANTUM DOTS;
G-C3N4;
HETEROJUNCTION;
LAFEO3/G-C3N4;
DEGRADATION;
NANOSHEETS;
D O I:
10.1002/cjce.23891
中图分类号:
TQ [化学工业];
学科分类号:
0817 ;
摘要:
In this paper, ultra-thin g-C3N4 nanosheets were prepared by improved ultrasonic stripping method for the first time. Then, g-C3N4 nanosheets were pretreated into Bi+/g-C3N4 nanosheets by electrostatic adsorption principle, and a new type of Cl-Bi2WO6/g-C3N4 heterostructure photocatalyst was prepared by using Bi+/g-C3N4 nanosheets as the substrate. The degradation of RhB under photocatalysis was studied with the compound amount of g-C3N4 and the amount of catalyst by using x-ray diffraction (XRD), a scanning electron microscope (SEM), high-resolution transmission electron microscopy (HRTEM), x-ray photoelectron spectroscopy (XPS), Brunauer Emmett-Teller (BET), and ultraviolet visible diffuse (UV-vis DRS) methods on the structure, morphology, and optical characterization charge transfer characteristics, etc. The results of the degradation experiment show that the compound appropriate amount of g-C3N4 can significantly improve the activity of the photocatalyst. At the same time, different amounts of Cl-Bi2WO6/g-C3N4 composite photocatalyst have a significant effect on the degradation performance, and the photocatalytic activity is the best when the input is 2 g/L. Combined with active species capture experiments, a possible degradation mechanism of Cl-Bi2WO6/g-C3N4 Z-type heterostructure photocatalyst was proposed.
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页码:2014 / 2023
页数:10
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