Microscopic characterisation of suspended graphene grown by chemical vapour deposition

被引:12
作者
Bignardi, Luca [1 ]
van Dorp, Willem F. [1 ]
Gottardi, Stefano [1 ]
Ivashenko, Oleksii [1 ]
Dudin, Pavel [2 ]
Barinov, Alexei [2 ]
De Hosson, Jeff Th. M. [1 ]
Stohr, Meike [1 ]
Rudolf, Petra [1 ]
机构
[1] Univ Groningen, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands
[2] Sinctrotrone Trieste Scpa, I-34149 Trieste, Italy
基金
欧洲研究理事会;
关键词
RAMAN-SPECTROSCOPY; SHEETS; CARBON; MEMBRANES;
D O I
10.1039/c3nr02386a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present a multi-technique characterisation of graphene grown by chemical vapour deposition (CVD) and thereafter transferred to and suspended on a grid for transmission electron microscopy (TEM). The properties of the electronic band structure are investigated by angle-resolved photoelectron spectromicroscopy, while the structural and crystalline properties are studied by TEM and Raman spectroscopy. We demonstrate that the suspended graphene membrane locally shows electronic properties comparable with those of samples prepared by micromechanical cleaving of graphite. Measurements show that the area of high quality suspended graphene is limited by the folding of the graphene during the transfer.
引用
收藏
页码:9057 / 9061
页数:5
相关论文
共 25 条
[1]   Honeycomb Carbon: A Review of Graphene [J].
Allen, Matthew J. ;
Tung, Vincent C. ;
Kaner, Richard B. .
CHEMICAL REVIEWS, 2010, 110 (01) :132-145
[2]   The surface science of graphene: Metal interfaces, CVD synthesis, nanoribbons, chemical modifications, and defects [J].
Batzill, Matthias .
SURFACE SCIENCE REPORTS, 2012, 67 (3-4) :83-115
[3]   Ultrahigh electron mobility in suspended graphene [J].
Bolotin, K. I. ;
Sikes, K. J. ;
Jiang, Z. ;
Klima, M. ;
Fudenberg, G. ;
Hone, J. ;
Kim, P. ;
Stormer, H. L. .
SOLID STATE COMMUNICATIONS, 2008, 146 (9-10) :351-355
[4]   Impermeable atomic membranes from graphene sheets [J].
Bunch, J. Scott ;
Verbridge, Scott S. ;
Alden, Jonathan S. ;
van der Zande, Arend M. ;
Parpia, Jeevak M. ;
Craighead, Harold G. ;
McEuen, Paul L. .
NANO LETTERS, 2008, 8 (08) :2458-2462
[5]   Influence of the atomic structure on the Raman spectra of graphite edges -: art. no. 247401 [J].
Cançado, LG ;
Pimenta, MA ;
Neves, BRA ;
Dantas, MSS ;
Jorio, A .
PHYSICAL REVIEW LETTERS, 2004, 93 (24)
[6]   The electronic properties of graphene [J].
Castro Neto, A. H. ;
Guinea, F. ;
Peres, N. M. R. ;
Novoselov, K. S. ;
Geim, A. K. .
REVIEWS OF MODERN PHYSICS, 2009, 81 (01) :109-162
[7]   Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy [J].
Dresselhaus, Mildred S. ;
Jorio, Ado ;
Hofmann, Mario ;
Dresselhaus, Gene ;
Saito, Riichiro .
NANO LETTERS, 2010, 10 (03) :751-758
[8]   Angle-resolved photoemission spectroscopy and imaging with a submicrometre probe at the SPECTROMICROSCOPY-3.2L beamline of Elettra [J].
Dudin, Pavel ;
Lacovig, Paolo ;
Fava, Claudio ;
Nicolini, Eugenio ;
Bianco, Anna ;
Cautero, Giuseppe ;
Barinov, Alexei .
JOURNAL OF SYNCHROTRON RADIATION, 2010, 17 :445-450
[9]  
Elias DC, 2011, NAT PHYS, V7, P701, DOI [10.1038/nphys2049, 10.1038/NPHYS2049]
[10]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)