One-Pot Synthesis of Dioxime Oxalates

被引：0

作者：

Adarve-Cardona, Laura ^{[1
]}

Ezenarro-Salcedo, David ^{[2
]}

Macias, Mario A. ^{[3
]}

Gamba-Sanchez, Diego ^{[1
]}

机构：

[1] Univ Los Andes, Chem Dept, Lab Organ Synth Bio & Organocatalysis, Cra 1 18A-12 Q 305, Bogota 111711, Colombia

[2] Univ Los Andes, Inorgan Chem Catalysis & Bioinorgan Grp, Chem Dept, Cra 1 18A-12, Bogota 111711, Colombia

[3] Univ Los Andes, CrisQuimMat, Crystallog & Chem Mat, Chem Dept, Cra 1 18A-12, Bogota 111711, Colombia

来源：

MOLBANK | 2022年 / 2022卷 / 04期

关键词：

dioxime oxalates; oximes; ketoximes; iminyl radicals; X-ray diffraction; VISIBLE-LIGHT; RADICALS; GENERATION; RESONANCE;

D O I：

10.3390/M1473

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dioxime oxalates, a type of carbonyl oximes, are well-known as clean sources of iminyl radicals that undergo key organic chemistry transformations. A series of dioxime oxalates is reported in this manuscript, obtained by the reaction of the corresponding oximes with oxalyl chloride and Et3N at room temperature. This one-pot method afforded three novel dioxime oxalates and the crystal structure of cyclopentanone dioxime oxalate analysis is also presented.

引用

页数：9

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