Detecting the origin of luminescence in Er3+-doped hexagonal Na1.5Gd1.5F6 phosphors

被引:35
作者
Wang, Xiangfu [1 ,2 ,3 ]
Bu, Yanyan [1 ]
Yan, Xiaohong [1 ]
Cai, Peiqing [2 ,3 ]
Wang, Jing [2 ,3 ]
Qin, Lin [2 ,3 ]
Thiquynh Vu [2 ,3 ]
Seo, Hyo Jin [2 ,3 ]
机构
[1] Nanjing Univ Posts & Telecommun, Sch Elect Sci & Engn, Nanjing 210023, Jiangsu, Peoples R China
[2] Pukyong Natl Univ, Dept Phys, Busan 608737, South Korea
[3] Pukyong Natl Univ, Interdisciplinary Program Biomed Mech & Elect Eng, Busan 608737, South Korea
基金
新加坡国家研究基金会; 中国国家自然科学基金;
关键词
SITE-SELECTIVE SPECTROSCOPY; UP-CONVERSION; NANOCRYSTALS;
D O I
10.1364/OL.41.005314
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Understanding site-selective fluorescence is one of valuable importance for spectrum modulation. In this Letter, we observed the existence of two non-equivalent Gd-activated crystallographic sites in an Er3+-doped hexagonal Na1.5Gd1.5F6 phosphor. It is proved that two green emissions from the S-4(3/2) level separately originate from the Gd1 (540 nm) and Na2/Gd2 (550-555 nm) crystallographic sites, and the 657 nm red emission from the F-4(9/2) level only originates from Na2/Gd2 site through using the time-resolved luminescence spectra. The 142.2% absolute enhancement of the red emission is realized through the synergistic effect of ultraviolet downconversion and infrared upconversion induced by the 370 nm and 1.54 mu m dual-mode excitation. (C) 2016 Optical Society of America
引用
收藏
页码:5314 / 5317
页数:4
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