Simple Technique for Spatially Separated Nanofibers/Nanobeads by Multinozzle Electrospinning toward White-Light Emission

被引:30
作者
Kim, Jongho [1 ]
Noh, Jaeguk [1 ]
Jo, Seonyoung [1 ]
Park, Ko Eun [1 ]
Park, Won Ho [1 ]
Lee, Taek Seung [1 ]
机构
[1] Chungnam Natl Univ, Dept Adv Organ Mat & Text Syst Engn, Organ & Optoelect Mat Lab, Taejon 306764, South Korea
基金
新加坡国家研究基金会;
关键词
electrospinning; nanofibers; white-light emission; fluorescence; multinozzle equipment; CONJUGATED POLYMER; EMITTING-DIODES; NANOFIBROUS MEMBRANES; DIRECT FABRICATION; ENERGY-TRANSFER; FLUOROPHORES; COMPOSITE; DEVICES; FIBERS; ELECTROLUMINESCENCE;
D O I
10.1021/am400782s
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Electrospun, emission color-tunable nanofibrous sheets were fabricated by multinozzle electrospinning equipped with a secondary electrode for the preparation of white-emissive sheets under a single excitation source, manipulating energy transfer between dyes. By control of the concentration of commercially available red, green, and blue dyes in the matrix polymer [poly(methyl methacrylate)], emission color tuning can be easily accomplished because each dye is located in spatially separated fibers to maintain enough distance to prevent or suppress energy transfer, allowing white-light emission. The application of dye separation for the whitelight emission upon excitation with a blue light-emitting-diode lamp is demonstrated, indicative of its potential application for the easy and facile tuning of fluorescence color toward flexible illumination.
引用
收藏
页码:6038 / 6044
页数:7
相关论文
共 52 条
  • [1] Use of electrospinning technique for biomedical applications
    Agarwal, Seema
    Wendorff, Joachim H.
    Greiner, Andreas
    [J]. POLYMER, 2008, 49 (26) : 5603 - 5621
  • [2] Electrospun nanofibers of blends of conjugated polymers: Morphology, optical properties, and field-effect transistors
    Babel, A
    Li, D
    Xia, YN
    Jenekhe, SA
    [J]. MACROMOLECULES, 2005, 38 (11) : 4705 - 4711
  • [3] Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
  • [4] Alignment of colloidal CdS nanowires embedded in polymer nanofibers by electrospinning
    Bashouti, M
    Salalha, W
    Brumer, M
    Zussman, E
    Lifshitz, E
    [J]. CHEMPHYSCHEM, 2006, 7 (01) : 102 - 106
  • [5] Electrospun polyalkylthiophene/polyethyleneoxide fibers: Optical characterization
    Bianco, Andrea
    Bertarelli, Chiara
    Frisk, Simon
    Rabolt, John F.
    Gallazzi, Maria C.
    Zerbi, Giuseppe
    [J]. SYNTHETIC METALS, 2007, 157 (6-7) : 276 - 281
  • [6] Bright, saturated, red-to-yellow organic light-emitting devices based on polarization-induced spectral shifts
    Bulovic, V
    Shoustikov, A
    Baldo, MA
    Bose, E
    Kozlov, VG
    Thompson, ME
    Forrest, SR
    [J]. CHEMICAL PHYSICS LETTERS, 1998, 287 (3-4) : 455 - 460
  • [7] Flexible active-matrix electronic ink display
    Chen, Y
    Au, J
    Kazlas, P
    Ritenour, A
    Gates, H
    McCreary, M
    [J]. NATURE, 2003, 423 (6936) : 136 - 136
  • [8] White organic light-emitting devices for solid-state lighting
    D'Andrade, BW
    Forrest, SR
    [J]. ADVANCED MATERIALS, 2004, 16 (18) : 1585 - 1595
  • [9] Nanofibers Doped with Dendritic Fluorophores for Protein Detection
    Davis, Bryce W.
    Niamnont, Nakorn
    Hare, Christopher D.
    Sukwattanasinitt, Mongkol
    Cheng, Quan
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (07) : 1798 - 1803
  • [10] Synthesis and assembly of metal nanoparticles on electrospun poly(4-vinylpyridine) fibers and poly(4-vinylpyridine) composite fibers
    Dong, H
    Fey, E
    Gandelman, A
    Jones, WE
    [J]. CHEMISTRY OF MATERIALS, 2006, 18 (08) : 2008 - 2011