High Performance Graphene/Ni2P Hybrid Anodes for Lithium and Sodium Storage through 3D Yolk-Shell-Like Nanostructural Design

被引：191
作者：
Wu, Chao [2 ]
Kopold, Peter [2 ]
van Aken, Peter A. [2 ]
Maier, Joachim [2 ]
Yu, Yan [1 ,2 ,3 ]
机构：
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Chinese Acad Sci, Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
[2] Max Planck Inst Solid State Res, Heisenbergstr 1, D-70569 Stuttgart, Germany
[3] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
来源：
ADVANCED MATERIALS | 2017年 / 29卷 / 03期
基金：
中国国家自然科学基金;
关键词：
ELECTROCHEMICAL PROPERTIES; ION BATTERIES; NI2P NANOPARTICLES; PAPER ELECTRODE; COMPOSITE PAPER; SHEETS; FABRICATION; NANOSHEETS; FILMS; NIO;
D O I：
10.1002/adma.201604015
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 3D yolk-shell-like electrode material composed of a porous interconnected graphene network and embedded Ni2P nanoparticles is designed and fabricated by an assembly and self-template strategy. This novel nanoarchitecture integrates the advantages of nano-structure and microstructure, and provides highly efficient and stable electrochemical circuits involving the active nano-particles, leading to excellent electrochemical performance in terms of reversibility, rate capability, and cycle stability.
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页数：7
相关论文
共 39 条
[1]   Novel peapod array of Ni2P@graphitized carbon fiber composites growing on Ti substrate: a superior material for Li-ion batteries and the hydrogen evolution reaction [J].
Bai, Yuanjuan ;
Zhang, Huijuan ;
Fang, Ling ;
Liu, Li ;
Qiu, Huajun ;
Wang, Yu .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (10) :5434-5441
[2]   Novel peapod-like Ni2P nanoparticles with improved electrochemical properties for hydrogen evolution and lithium storage [J].
Bai, Yuanjuan ;
Zhang, Huijuan ;
Li, Xiao ;
Liu, Li ;
Xu, Haitao ;
Qiu, Huajun ;
Wang, Yu .
NANOSCALE, 2015, 7 (04) :1446-1453
[3]   Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions [J].
Cabana, Jordi ;
Monconduit, Laure ;
Larcher, Dominique ;
Rosa Palacin, M. .
ADVANCED MATERIALS, 2010, 22 (35) :E170-E192
[4]   Improving the Li-Electrochemical Properties of Monodisperse Ni2P Nanoparticles by Self-Generated Carbon Coating [J].
Carenco, S. ;
Surcin, C. ;
Morcrette, M. ;
Larcher, D. ;
Mezailles, N. ;
Boissiere, C. ;
Sanchez, C. .
CHEMISTRY OF MATERIALS, 2012, 24 (04) :688-697
[5]   Nanoscaled Metal Borides and Phosphides: Recent Developments and Perspectives [J].
Carenco, Sophie ;
Portehault, David ;
Boissiere, Cedric ;
Mezailles, Nicolas ;
Sanchez, Clement .
CHEMICAL REVIEWS, 2013, 113 (10) :7981-8065
[6]   Mechanically strong, electrically conductive, and biocompatible graphene paper [J].
Chen, Haiqun ;
Mueller, Marc B. ;
Gilmore, Kerry J. ;
Wallace, Gordon G. ;
Li, Dan .
ADVANCED MATERIALS, 2008, 20 (18) :3557-+
[7]   Electrochemical properties of electrodeposited nicked phosphide thin films in lithium cells [J].
Cruz, Manuel ;
Morales, Julian ;
Sanchez, Luis ;
Santos-Pena, Jesus ;
Martin, Francisco .
JOURNAL OF POWER SOURCES, 2007, 171 (02) :870-878
[8]   Polymer-Derived Ceramic Functionalized MoS2 Composite Paper as a Stable Lithium-Ion Battery Electrode [J].
David, L. ;
Bhandavat, R. ;
Barrera, U. ;
Singh, G. .
SCIENTIFIC REPORTS, 2015, 5
[9]   Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries [J].
David, Lamuel ;
Bhandavat, Romil ;
Barrera, Uriel ;
Singh, Gurpreet .
NATURE COMMUNICATIONS, 2016, 7
[10]   Reduced Graphene Oxide Paper Electrode: Opposing Effect of Thermal Annealing on Li and Na Cyclability [J].
David, Lamuel ;
Singh, Gurpreet .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (49) :28401-28408
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