VISCOSITY MODELING FOR IONIC LIQUID SOLUTIONS BY EYRING-WILSON EQUATION

被引：26
|
作者：
He, Yang-Chun [1 ]
Xu, Xue-Jiao [1 ]
Yang, Li-Jun [1 ]
Ding, Bing [1 ]
机构：
[1] Zhejiang Gongshang Univ, Coll Food Sci & Biotechnol Engn, Hangzhou, Zhejiang, Peoples R China
来源：
CHEMICAL INDUSTRY & CHEMICAL ENGINEERING QUARTERLY | 2012年 / 18卷 / 03期
关键词：
ionic liquids; viscosity; Wilson Equation; green solvent; 1-ETHYL-3-METHYLIMIDAZOLIUM ETHYL SULFATE; EXCESS MOLAR VOLUMES; BINARY-MIXTURES; PHYSICAL-PROPERTIES; 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE; 1-METHYL-3-OCTYLIMIDAZOLIUM TETRAFLUOROBORATE; ACTIVITY-COEFFICIENTS; ELECTROLYTE-NRTL; FREE-ENERGY; 328.15; K;
D O I：
10.2298/CICEQ110829019H
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A semi-theoretical model based on the classical Eyring's mixture viscosity equation and the Wilson activity coefficient equation is presented for correlating the viscosity of ionic liquids with solvent systems. The accuracy of the proposed model was verified by comparing calculated and experimental viscosity values from the literature for 49 mixtures with,a total of 1560 data points. The results show that the equation, similar to the Wilson activity coefficient equation, can be well applied to describe the non-ideal term in the Eyring's mixture viscosity equation. The model has a relatively simple mathematical form and can be easily incorporated into process simulation software.
引用
收藏
页码：441 / 447
页数：7
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