Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts

被引：1748
作者：
Feng, Dawei [1 ]
Gu, Zhi-Yuan [1 ]
Li, Jian-Rong [1 ,2 ]
Jiang, Hai-Long [1 ]
Wei, Zhangwen [1 ]
Zhou, Hong-Cai [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[2] Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 41期
关键词：
biomimetic catalyst; mesoporous materials; metal-organic frameworks; oxidation; zirconium; PORPHYRIN; HEME; OXIDATION; ENZYMES; SERIES; CAGES;
D O I：
10.1002/anie.201204475
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Biomimetic MOF: Extremely stable MOFs with different open metal sites and ultra-large 1D channels, PCN-222 (Fe, Mn, Co, Ni, Cu, and Zn), have been assembled with eight-connected Zr6 clusters and redox-active metalloporphyrin motifs. PCN-222(Fe) shows peroxidase-like activity in aqueous solution, exhibiting highly effective biomimetic oxidation on a number of substrates. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10307 / 10310
页数：4
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