Improvement of pesticide adsorption capacity of cellulose fibre by high-energy irradiation-initiated grafting of glycidyl methacrylate

被引:14
作者
Takacs, Erzsebet [3 ]
Wojnarovits, Laszlo [3 ]
Horvath, Eva Koczog [3 ]
Fekete, Tamas [1 ,3 ]
Borsa, Judit [1 ,2 ]
机构
[1] Budapest Univ Technol & Econ, H-1521 Budapest, Hungary
[2] Obuda Univ, H-1034 Budapest, Hungary
[3] Hungarian Acad Sci, Inst Isotopes, H-1525 Budapest, Hungary
基金
匈牙利科学研究基金会;
关键词
Grafting; Radiation initiation; Cellulose; Adsorption; Freundlich isotherm; CYCLODEXTRIN IMMOBILIZATION; RADIATION; FUNCTIONALIZATION; POLYMERIZATION; POLLUTANTS; PHENOL; WASTE; WATER;
D O I
10.1016/j.radphyschem.2011.11.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cellulose as a renewable raw material was used for preparation of adsorbent of organic impurities in wastewater treatment. Hydrophobic surface of cellulose substrate was developed by grafting glycidyl methacrylate in simultaneous grafting using gamma irradiation initiation. Water uptake of cellulose significantly decreased while adsorption of phenol and a pesticide molecule (2,4-dichlorophenoxyacetic acid: 2,4-D) increased upon grafting. Adsorption equilibrium data fitted the Freundlich isotherm for both solutes. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1389 / 1392
页数:4
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