Manipulating Replication Processes within a Dynamic Covalent Framework

被引：36
作者：
del Amo, Vicente
Slawin, Alexandra M. Z.
Philp, Douglas [1 ]
机构：
[1] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland
来源：
ORGANIC LETTERS | 2008年 / 10卷 / 20期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1021/ol8018665
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of an amine bearing an amidopyridine recognition site and an aldehyde bearing a carboxylic acid recognition site affords an imine that is capable of directing its own formation through a dynamic covalent replication cycle. Additionally, the amine, formed by reduction of the replicating imine, is a more efficient catalyst for the formation of the replicating imine than the imine is a catalyst for its own formation.
引用
收藏
页码：4589 / 4592
页数：4
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