Oxidation of Fe-10Cr in O2 and in O2+H2O environment at 600 °C: A microstructural investigation

被引：54
|
作者：
Jonsson, T. [1 ]
Pujilaksono, B. [1 ]
Heidari, H. [2 ]
Liu, F. [2 ]
Svensson, J. -E. [1 ]
Halvarsson, M. [2 ]
Johansson, L-G. [1 ]
机构：
[1] Chalmers, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden
[2] Chalmers, Dept Appl Phys, SE-41296 Gothenburg, Sweden
来源：
CORROSION SCIENCE | 2013年 / 75卷
关键词：
Stainless steel; TEM; STEM; High temperature corrosion; Internal oxidation; HIGH-TEMPERATURE OXIDATION; IRON-CHROMIUM ALLOYS; WATER-VAPOR; FECR-ALLOYS; FLOW-RATE; 600-DEGREES-C; SCALE; EVAPORATION; KINETICS; OXYGEN;
D O I：
10.1016/j.corsci.2013.06.016
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Oxidation of Fe-10Cr in dry and wet O-2 was studied at 600 degrees C for up to 168 h. Oxide microstructure was investigated by STEM/EDX, FIB/SEM and TEM. Oxidation in dry O-2 gives a Cr-rich protective (Fe1-xCrx)(2)O-3 scale. The same protective oxide initially forms in O-2 + H2O environment, but after an incubation period scale breakdown is triggered by CrO2(OH)(2) evaporation that depletes the substrate in Cr and converts (Fe1-xCrx)(2)O-3 to FeCr spinel oxide. Internal oxidation occurs after breakaway. Alternating external and internal oxidation result in the inward-growing scale showing a characteristic banded morphology. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：326 / 336
页数：11
相关论文
共 50 条
  • [1] Oxidation of Binary FeCr Alloys (Fe-2.25Cr, Fe-10Cr, Fe-18Cr and Fe-25Cr) in O2 and in O2 + H2O Environment at 600 °C
    Pujilaksono, B.
    Jonsson, T.
    Heidari, H.
    Halvarsson, M.
    Svensson, J. -E.
    Johansson, L. -G.
    OXIDATION OF METALS, 2011, 75 (3-4): : 183 - 207
  • [2] Oxidation of Sanicro 25 (42Fe22Cr25NiWCuNbN) in O2 and O2 + H2O Environments at 600-750 A°C
    Intiso, L.
    Johansson, L. -G.
    Svensson, J. -E.
    Halvarsson, M.
    OXIDATION OF METALS, 2015, 83 (3-4): : 367 - 391
  • [3] The influence of Si on the primary protection of lean FeCrAl model alloys in O2 and O2+ H2O at 600 °C-A microstructural investigation
    Asokan, V.
    Eklund, J.
    Bigdeli, S.
    Jonsson, T.
    CORROSION SCIENCE, 2021, 179
  • [4] Oxidation Behaviour of Sanicro 25 (42Fe22Cr25NiWCuNbN) in O2/H2O Mixture at 600 °C
    Intiso, L.
    Johansson, L. -G.
    Canovic, S.
    Bellini, S.
    Svensson, J. -E.
    Halvarsson, M.
    OXIDATION OF METALS, 2012, 77 (5-6): : 209 - 235
  • [5] Corrosion Behaviors of Ni-Cr Alloys in O2, H2O and H2O + O2 Gases at 700°C and the Effect of Temperature
    Chen, Jiarui
    Jiang, Chengyang
    Zhang, Jianqiang
    HIGH TEMPERATURE CORROSION OF MATERIALS, 2023, 100 (5-6) : 775 - 789
  • [6] Oxygen exchange in oxidation of an Fe-20Cr-10Al alloy in ∼10 mbar O2/H2O-gas mixtures at 920°C
    T. Åkermark
    G. Hultquist
    Oxidation of Metals, 1997, 47 : 117 - 137
  • [7] Oxidation of a Fe-18Cr-8Ni austenitic stainless steel at 850 °C in O2: Microstructure evolution during breakaway oxidation
    Col, Audrey
    Parry, Valerie
    Pascal, Celine
    CORROSION SCIENCE, 2017, 114 : 17 - 27
  • [8] Oxidation of FeCrAl foils at 500-900°C in dry O2 and O2 with 40% H2O
    Engkvist, J.
    Canovic, S.
    Liu, F.
    Gotlind, H.
    Svensson, J. -E.
    Johansson, L. -G.
    Olsson, M.
    Halvarsson, M.
    MATERIALS AT HIGH TEMPERATURES, 2009, 26 (02) : 199 - 210
  • [9] Competition between O2 and H2O2 in the oxidation of Fe(II) in natural waters
    González-Dávila, M
    Santana-Casiano, JM
    Millero, FJ
    JOURNAL OF SOLUTION CHEMISTRY, 2006, 35 (01) : 95 - 111
  • [10] Microstructural Investigation of the Initial Oxidation of the FeCrAlRE Alloy Kanthal AF in Dry and Wet O2 at 600 and 800°C
    Canovic, S.
    Engkvist, J.
    Liu, F.
    Lai, H.
    Gotlind, H.
    Hellstrom, K.
    Svensson, J. -E.
    Johansson, L. -G.
    Olsson, M.
    Halvarsson, M.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (06) : C223 - C230
12345