Thermogravimetric investigation of hydrochar-lignite co-combustion

被引:156
作者
Liu, Zhengang [1 ]
Quek, Augustine [1 ]
Hoekman, S. Kent [2 ]
Srinivasan, M. P. [3 ]
Balasubramanian, R. [1 ]
机构
[1] Natl Univ Singapore, Dept Civil & Environm Engn, Singapore 117576, Singapore
[2] DRI, Div Atmospher Sci, Reno, NV 89512 USA
[3] Natl Univ Singapore Blk ES, Dept Chem & Biomol Engn, Singapore 117576, Singapore
关键词
Hydrochar; Co-combustion; Lignite; Thermogravimetric analysis; HYDROTHERMAL CARBONIZATION; BIOMASS; COAL; COMBUSTION; REACTIVITY; QUALITY; BLENDS;
D O I
10.1016/j.biortech.2012.06.063
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Co-combustion of hydrochar with lignite was investigated by means of thermogravimetric analysis. Hydrochars were produced from coconut fibers and eucalyptus leaves under hydrothermal conditions at 250 degrees C. The hydrochar was added in varying amounts to lignite for combustion. The results indicated that hydrothermal treatment decreased the volatile matter content and increased the fixed carbon content of the biomaterials. The elevated energy density and decreased ash content of the hydrochar improved its combustion behavior when co-fired with lignite for energy production. The hydrochars derived from coconut fiber and eucalyptus leaves had similar chemical compositions and showed similar influences on lignite combustion. Hydrochar addition increased the burnout and shortened the combustion range of the hydrochar-lignite blends. High combustion efficiency was observed due to the synergistic interactions between hydrochar and lignite during the co-combustion process. A kinetic study showed that the combustion process of hydrochar-lignite blends followed first-order reaction rates. (C) 2012 Published by Elsevier Ltd.
引用
收藏
页码:646 / 652
页数:7
相关论文
共 29 条
[1]   Biochar as a Fuel: 2. Significant Differences in Fuel Quality and Ash Properties of Biochars from Various Biomass Components of Mallee Trees [J].
Abdullah, Hanisom ;
Mediaswanti, Kun Aussieanita ;
Wu, Hongwei .
ENERGY & FUELS, 2010, 24 (03) :1972-1979
[2]  
[Anonymous], 2009, Tech. Rep. No. INL/EXT- 09-15423
[3]   Co-combustion of peach and apricot stone with coal in a bubbling fluidized bed [J].
Atimtay, Aysel T. ;
Kaynak, Burcak .
FUEL PROCESSING TECHNOLOGY, 2008, 89 (02) :183-197
[4]   A unified correlation for estimating HHV of solid, liquid and gaseous fuels [J].
Channiwala, SA ;
Parikh, PP .
FUEL, 2002, 81 (08) :1051-1063
[5]   Combustion characteristics of different biomass fuels [J].
Demirbas, A .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2004, 30 (02) :219-230
[6]   Hydrothermal carbonization of biomass: A summary and discussion of chemical mechanisms for process engineering [J].
Funke, Axel ;
Ziegler, Felix .
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2010, 4 (02) :160-177
[7]   Thermal behaviour and kinetics of coal/biomass blends during co-combustion [J].
Gil, M. V. ;
Casal, D. ;
Pevida, C. ;
Pis, J. J. ;
Rubiera, F. .
BIORESOURCE TECHNOLOGY, 2010, 101 (14) :5601-5608
[8]   Combustion characteristics of different biomass materials [J].
Haykiri-Açma, H .
ENERGY CONVERSION AND MANAGEMENT, 2003, 44 (01) :155-162
[9]   Combustion reactivity of different rank coals [J].
Haykiri-Açma, H ;
Ersoy-Meriçboyu, A ;
Küçükbayrak, S .
ENERGY CONVERSION AND MANAGEMENT, 2002, 43 (04) :459-465
[10]   Effect of biomass on burnouts of Turkish lignites during co-firing [J].
Haykiri-Acma, H. ;
Yaman, S. .
ENERGY CONVERSION AND MANAGEMENT, 2009, 50 (09) :2422-2427