Single-step extraction of small-diameter single-walled carbon nanotubes in the presence of riboflavin

被引：2

作者：

Kalachikova, Polina M. ^{[1
,2
]}

Goldt, Anastasia E. ^{[1
]}

Khabushev, Eldar M. ^{[1
,2
]}

V. Eremin, Timofei ^{[3
,4
]}

Zatsepin, Timofei S. ^{[1
,5
]}

Obraztsova, Elena D. ^{[3
,4
]}

V. Larionov, Konstantin ^{[6
]}

Antipina, Liubov Yu. ^{[7
]}

Sorokin, Pavel B. ^{[7
]}

Nasibulin, Albert G. ^{[1
,2
]}

机构：

[1] Skolkovo Inst Sci & Technol, 3 Nobel St, Moscow 121205, Russia

[2] Aalto Univ Sch Chem Engn, Kemistintie 1, Espoo 02015, Finland

[3] AM Prokhorov Gen Phys Inst RAS, 38 Vavilov St, Moscow 119991, Russia

[4] Moscow Inst Phys & Technol, 9 Institutskiy Per, Dolgoprudnyi 141701, Russia

[5] MVLomonosov Moscow State Univ, Dept Chem, Moscow 119992, Russia

[6] Natl Univ Sci & Technol MISiS, 4 Leninsky prospect, Moscow 119049, Russia

[7] Russian Acad Sci, Emanuel Inst Biochem Phys, 4 Kosygina st, Moscow 119334, Russia

来源：

BEILSTEIN JOURNAL OF NANOTECHNOLOGY | 2022年 / 13卷

基金：

俄罗斯科学基金会;

关键词：

carbon nanotubes; photoluminescence spectroscopy; riboflavin; size exclusive gel chromatography; SWCNT extraction; RECOGNITION; SEPARATION; COMPLEXES;

D O I：

10.3762/bjnano.13.130

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We propose a novel approach to disperse and extract small-diameter single-walled carbon nanotubes (SWCNTs) using an aqueous solution of riboflavin and Sephacryl gel. The extraction of small-diameter semiconducting SWCNTs was observed, regardless of the initial diameter distribution of the SWCNTs. Dispersion of SWCNTs occurs due to the adsorption of pi-conjugated isoallox-azine moieties on the surface of small-diameter nanotubes and interactions between hydroxy groups of ribityl chains with water. During the SWCNT extraction, specific adsorption of riboflavin to SWCNTs leads to the minimization of interactions between the SWCNTs and gel media. Our experimental findings are supported by ab initio calculations demonstrating the impact of the riboflavin wrapping pattern around the SWCNTs on their interaction with the allyl dextran gel.

引用

页码：1564 / 1571

页数：8

共 37 条

[1] Achieving Extremely Concentrated Aqueous Dispersions of Graphene Flakes and Catalytically Efficient Graphene-Metal Nanoparticle Hybrids with Flavin Mononucleotide as a HighPerformance Stabilizer [J].

Ayan-Varela, M. ;

Paredes, J. I. ;

Guardia, L. ;

Villar-Rodil, S. ;

Munuera, J. M. ;

Diaz-Gonzalez, M. ;

Fernandez-Sanchez, C. ;

Martinez-Alonso, A. ;

Tascon, J. M. D. .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (19) :10293-10307

[2] Narrow (n,m)-distribution of single-walled carbon nanotubes grown using a solid supported catalyst [J].

Bachilo, SM ;

Balzano, L ;

Herrera, JE ;

Pompeo, F ;

Resasco, DE ;

Weisman, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) :11186-11187

[3] Evaluation of Riboflavin Transporters as Targets for Drug Delivery and Theranostics [J].

Bartmann, Lisa ;

Schumacher, David ;

von Stillfried, Saskia ;

Sternkopf, Marieke ;

Alampour-Rajabi, Setareh ;

van Zandvoort, Marc A. M. J. ;

Kiessling, Fabian ;

Wu, Zhuojun .

FRONTIERS IN PHARMACOLOGY, 2019, 10

[4] Synthesis, purification, properties and characterization of sorted single-walled carbon nanotubes [J].

Bati, Abdulaziz S. R. ;

Yu, LePing ;

Batmunkh, Munkhbayar ;

Shapter, Joseph G. .

NANOSCALE, 2018, 10 (47) :22087-22139

[5] Dispersions of carbon nanotubes by helical flavin surfactants: Solvent induced stability and chirality enrichment, and solvatochromism [J].

Choi, In-Seung ;

Park, Minsuk ;

Koo, Eunhye ;

Ju, Sang-Yong .

CARBON, 2021, 184 :346-356

[6] Riboflavin-Targeted Drug Delivery [J].

Darguzyte, Milita ;

Drude, Natascha ;

Lammers, Twan ;

Kiessling, Fabian .

CANCERS, 2020, 12 (02)

[7]

Dresselhaus M.S., 1996, Science of Fullerenes and Carbon Nanotubes

[8] Diameter-Dependent Solubility of Single-Walled Carbon Nanotubes [J].

Duque, Juan G. ;

Parra-Vasquez, A. Nicholas G. ;

Behabtu, Natnael ;

Green, Micah J. ;

Higginbotham, Amanda L. ;

Price, B. Katherine ;

Leonard, Ashley D. ;

Schmidt, Howard K. ;

Lounis, Brahim ;

Tour, James M. ;

Doorn, Stephen K. ;

Cognet, Laurent ;

Pasquali, Matteo .

ACS NANO, 2010, 4 (06) :3063-3072

[9] Photoswitchable single-walled carbon nanotubes for super-resolution microscopy in the near-infrared [J].

Godin, Antoine G. ;

Setaro, Antonio ;

Gandil, Morgane ;

Haag, Rainer ;

Adeli, Mohsen ;

Reich, Stephanie ;

Cognet, Laurent .

SCIENCE ADVANCES, 2019, 5 (09)

[10] Accurate description of van der Waals complexes by density functional theory including empirical corrections [J].

Grimme, S .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 2004, 25 (12) :1463-1473

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