Silicon semiconductor-assisted Bronsted acid-catalyzed dehydration: Highly selective synthesis of 5-hydroxymethylfurfural from fructose under visible light irradiation

被引：29

作者：

Tsutsumi, Ken ^{[1
]}

Kurata, Natsuki ^{[1
]}

Takata, Eri ^{[1
]}

Furuichi, Kayo ^{[1
]}

Nagano, Masaru ^{[1
]}

Tabata, Kenji ^{[1
]}

机构：

[1] Miyazaki Univ, Fac Engn, Dept Appl Chem, Miyazaki 8892155, Japan

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2014年 / 147卷

关键词：

Semiconductor; Dehydration; Selective synthesis; Silicon; 5-Hydroxymethylfurfural; ORGANIC-COMPOUNDS; LEVULINIC ACID; CONVERSION; WATER; PHOTOCATALYSIS; GLUCOSE; 5-HYDROXYMETHYL-2-FURALDEHYDE; DECOMPOSITION; MECHANISM; TIO2;

D O I：

10.1016/j.apcatb.2013.10.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Semiconductor materials are used to promote Bronsted acid-catalyzed dehydration of fructose to 5-hydroxymethylfurfural (HMF) under visible light irradiation. In the proposed reaction system the semiconductors convert light to heat, transferring chemical energy to the substrates. We found that silicon was a more suitable semiconductor for the conversion of fructose to HMF compared with alpha-Fe2O3, WO3, and TiO2. Remarkably, a silicon semiconductor coated with silanol groups (Si-OH) affords HMF in almost quantitative yield (97%) even at 80 degrees C. This result suggests that the Si-OH catalyst provides energy selectively to the starting material fructose and not to desired product HMF, preventing side-reactions. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：1009 / 1014

页数：6

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