Allylation of aldehydes via Umpolung of π-allylpalladium(II) with triethylborane

被引：38
|
作者：
Kimura, M [1 ]
Kiyama, I [1 ]
Tomizawa, T [1 ]
Horino, Y [1 ]
Tanaka, S [1 ]
Tamaru, Y [1 ]
机构：
[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 8528521, Japan
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 37期
关键词：
aldehydes; allylation; boron; boron compounds; palladium; palladium compounds;
D O I：
10.1016/S0040-4039(99)01359-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Triethylborane induces allylic substrates (benzoates, phenyl ethers, benzyl ethers, but not halides) to undergo allylation of aldehydes in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) The reaction proceeds via Umpolung of pi-allylpalladium. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6795 / 6798
页数：4
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