A 10-connected coordination network based on the planar tetranuclear cobalt cluster building blocks: synthesis, structure, and magnetism

被引：14
|
作者：
Cao, Hai-Yan [1 ]
Liu, Qing-Yan [1 ]
Liu, Cai-Ming [2 ]
Wang, Yu-Ling [1 ]
Chen, Li-Li [1 ]
Xiong, Li-Hua [1 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China
[2] Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 34卷
关键词：
10-connected network; Co(II) coordination polymer; (3(6).4(34).5(3).6(2)) topology; Magnetism; METAL; TOPOLOGIES; FRAMEWORK; POLYMERS; CRYSTAL; LIGANDS; MOFS;
D O I：
10.1016/j.inoche.2013.04.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A coordination polymer [Co-4(mu(2)-H2O)(2)(1,4-ndc)(4)(dpp)(2)](n) (1) with the 1,4-naphthalenedicarboxylic acid (1,4-H(2)ndc) and 1,3-di(4-pyridyl)propane (dpp) mixed ligands has been synthesized and structurally and magnetically characterized. Compound 1 features a 3D framework based on the tetranuclear [Co-4(mu(2)-H2O)(2)(COO)(6)] secondary building units (SBUs) where the four cobalt ions are coplanar. The 3D coordination network of 1 is a rare 10-connected network of (3(6).4(34).5(3).6(2)) topology based on the tetranuclear cobalt cluster nodes. Magnetic measurements on compound 1 indicate that there is a net antiferromagnetic coupling among the Co(II) ions. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：12 / 14
页数：3
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