Mn(II) metal-organic frameworks based on Mn3 clusters: from 2D layer to 3D framework by the "pillaring" approach

被引：65
|
作者：
Chen, Yong-Qiang [1 ]
Liu, Sui-Jun
Li, Yun-Wu
Li, Guo-Rong
He, Kun-Huan
Chang, Ze
Bu, Xian-He
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CRYSTENGCOMM | 2013年 / 15卷 / 08期
基金：
美国国家科学基金会;
关键词：
TRIPODAL FLEXIBLE LIGAND; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; HYBRID FRAMEWORKS; NETWORK; SERIES; CONSTRUCTION; ADSORPTION; DIVERSITY;
D O I：
10.1039/c2ce26734a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two complexes {[Mn-3(btcit)(2)(H2O)(2)(DMF)(2)]center dot 2DMF}(infinity) (1) and {[Mn-3(btcit)(2)(bib)(2)]center dot 2DMF}(infinity) (2) (H(3)btcit = 4,4',4 ''-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid, bib = 1,4-bis(imidazol-1-yl)benzene) were obtained under the same reaction condition. Complex 1 is a two dimensional (4,4) network constructed from linear Mn-3 units and btcit ligands. Complex 2, which presents an interesting two-fold interpenetrating three dimensional framework with fsf topology, was obtained by modifying complex 1 with a "pillaring'' approach. Moreover, the magnetic properties of 1 and 2 have been investigated and both of them show antiferromagnetic behaviour.
引用
收藏
页码：1613 / 1617
页数：5
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