Annealing behavior of ultrahigh molecular weight polyethylene investigated by confocal micro-Raman spectroscopy combined with two-dimensional correlation spectroscopy

被引：3

作者：

Lu, Peidong ^{[1
]}

He, Ting ^{[1
]}

机构：

[1] Beijing Inst Technol, Inst Chem Phys, 5 South Zhongguancun St, Beijing 100081, Peoples R China

来源：

INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION | 2017年 / 22卷 / 01期

关键词：

Annealing; confocal micro-Raman; two-dimensional correlation spectroscopy; ultrahigh molecular weight polyethylene; HIGH-DENSITY POLYETHYLENE; CRYSTALLIZED POLYETHYLENE; PHASE-COMPOSITION; TEMPERATURE; MORPHOLOGY; POLY(3-HYDROXYALKANOATES); HOMOPOLYMER; THICKNESS; MOBILITY; DOMAINS;

D O I：

10.1080/1023666X.2016.1222479

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Annealing was performed for ultrahigh molecular weight polyethylene (UHMWPE), including an isothermal process at 110.0 degrees C and cooling process from 110.0 to 30.0 degrees C. The processes were in situ investigated by confocal micro-Raman spectroscopy combined with two-dimensional correlation spectroscopy. Two phase transitions were directly observed in the annealing processes, i.e., from the amorphous phase to the intermediate phase and from the intermediate phase to the crystalline phase. The phase transitions derive from molecular chain segments sliding between different phases of UHMWPE and occur in different orders during the isothermal and cooling processes.

引用

页码：17 / 26

页数：10

共 35 条

[1] Ultra-high molecular weight polyethylene - Evidence for a three-phase morphology [J].

Barron, D. ;

Birkinshaw, C. .

POLYMER, 2008, 49 (13-14) :3111-3115

[2] Rapidly cooled polyethylenes: On the thermal stability of the semicrystalline morphology [J].

Basiura, M. ;

Gearba, R. I. ;

Ivanov, D. A. ;

Janicki, J. ;

Reynaers, H. ;

Groeninckx, G. ;

Bras, W. ;

Goderis, B. .

MACROMOLECULES, 2006, 39 (24) :8399-8411

[3] Continued Improved Wear with an Annealed Highly Cross-linked Polyethylene [J].

Capello, William N. ;

D'Antonio, James A. ;

Ramakrishnan, Rama ;

Naughton, Marybeth .

CLINICAL ORTHOPAEDICS AND RELATED RESEARCH, 2011, 469 (03) :825-830

[4] Crystal morphology of strained ultra high molecular weight polyethylenes [J].

Collins, Maurice N. ;

Dalton, Eric ;

Schaller, Barbara ;

Leahy, J. J. ;

Birkinshaw, Colin .

POLYMER TESTING, 2012, 31 (05) :629-637

[5] Effect of annealing on the viscoelastic and viscoplastic responses of low-density polyethylene [J].

Drozdov, AD ;

Yuan, Q .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (14) :1638-1655

[6] A study on solid-state drawn fibers of polyethylene by confocal Raman microspectrometry: evaluation of the orientation profiles of amorphous and crystalline phases across the fiber section [J].

Fagnano, C ;

Rossi, M ;

Porter, RS ;

Ottani, S .

POLYMER, 2001, 42 (13) :5871-5883

[7]

Gardiner D, 1989, Practical Raman Spectroscopy

[8] Effect of temperature and annealing on the phase composition, molecular mobility, and the thickness of domains in isotactic polypropylene studied by proton solid-state NMR, SAXS, and DSC [J].

Hedesiu, C. ;

Demco, D. E. ;

Kleppinger, R. ;

Vanden Poel, G. ;

Gijsbers, W. ;

Bluemich, B. ;

Remerie, K. ;

Litvinov, V. M. .

MACROMOLECULES, 2007, 40 (11) :3977-3989

[9] The effect of temperature and annealing on the phase composition, molecular mobility and the thickness of domains in high-density polyethylene [J].

Hedesiu, Cristian ;

Demco, Dan E. ;

Kleppinger, Ralph ;

Buda, Alina Adams ;

Bluemich, Bernhard ;

Remerie, Klaas ;

Litvinov, Victor M. .

POLYMER, 2007, 48 (03) :763-777

[10] THICKENING PROCESS OF POLYETHYLENE SINGLE-CRYSTALS AT AN EARLY STAGE OF ANNEALING .2. COMPUTER-SIMULATION OF LAMELLAR THICKENING [J].

ICHIDA, T ;

TSUJI, M ;

MURAKAMI, S ;

KAWAGUCHI, A ;

KATAYAMA, K .

COLLOID AND POLYMER SCIENCE, 1985, 263 (04) :293-300

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