Mechanocatalytic depolymerization of cellulose combined with hydrogenolysis as a highly efficient pathway to sugar alcohols

被引：136

作者：

Hilgert, Jakob ^{[1
]}

Meine, Niklas ^{[1
]}

Rinaldi, Roberto ^{[1
]}

Schueth, Ferdi ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2013年 / 6卷 / 01期

关键词：

NONTHERMAL ATMOSPHERIC PLASMA; CATALYTIC CONVERSION; HYDROGENATION; HYDROLYSIS; RUTHENIUM; SORBITOL; CARBON; ACIDS;

D O I：

10.1039/c2ee23057g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cellulose is both insoluble in water and resistant against hydrolysis. These features pose major problems for its conversion into platform chemicals. Herein, we demonstrate that mechanocatalytic, solid-state depolymerization combined with hydrogenolysis, in the presence of Ru/C in water, provides a highly efficient pathway for the production of sugar alcohols. This novel approach leads to yields of hexitols up to 94% at 150 degrees C in an overall process time of 4 h.

引用

页码：92 / 96

页数：5

共 31 条

[11] Direct conversion of cellulose into sorbitol using dual-functionalized catalysts in neutral aqueous solution [J].

Han, Joung Woo ;

Lee, Hyunjoo .

CATALYSIS COMMUNICATIONS, 2012, 19 :115-118

[12] Mechanocatalysis for biomass-derived chemicals and fuels [J].

Hick, Sandra M. ;

Griebel, Carolin ;

Restrepo, David T. ;

Truitt, Joshua H. ;

Buker, Eric J. ;

Bylda, Caroline ;

Blair, Richard G. .

GREEN CHEMISTRY, 2010, 12 (03) :468-474

[13] Liquid-phase dehydration of sorbitol under microwave irradiation in the presence of acidic resin catalysts [J].

Khan, Nazmul Abedin ;

Mishra, Dinesh Kumar ;

Hwang, Jin-Soo ;

Kwak, Young-Woo ;

Jhung, Sung Hwa .

RESEARCH ON CHEMICAL INTERMEDIATES, 2011, 37 (09) :1231-1238

[14] Transfer hydrogenation of cellulose to sugar alcohols over supported ruthenium catalysts [J].

Kobayashi, Hirokazu ;

Matsuhashi, Hisateru ;

Komanoya, Tasuku ;

Hara, Kenji ;

Fukuoka, Atsushi .

CHEMICAL COMMUNICATIONS, 2011, 47 (08) :2366-2368

[15] Synthesis of sugar alcohols by hydrolytic hydrogenation of cellulose over supported metal catalysts [J].

Kobayashi, Hirokazu ;

Ito, Yukiko ;

Komanoya, Tasuku ;

Hosaka, Yuto ;

Dhepe, Paresh L. ;

Kasai, Koji ;

Hara, Kenji ;

Fukuoka, Atsushi .

GREEN CHEMISTRY, 2011, 13 (02) :326-333

[16] CHARACTERIZATION OF RUTHENIUM CATALYSTS AS STUDIED BY TEMPERATURE PROGRAMMED REDUCTION [J].

KOOPMAN, PGJ ;

KIEBOOM, APG ;

VANBEKKUM, H .

JOURNAL OF CATALYSIS, 1981, 69 (01) :172-179

[17] INDUCTION EFFECTS IN LIQUID-PHASE HYDROGENATION CATALYZED BY RUTHENIUM ON CARBON [J].

KOOPMAN, PGJ ;

KIEBOOM, APG ;

VANBEKKUM, H .

COLLOIDS AND SURFACES, 1981, 3 (01) :1-12

[18] Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production [J].

Kumar, Parveen ;

Barrett, Diane M. ;

Delwiche, Michael J. ;

Stroeve, Pieter .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (08) :3713-3729

[19] Renewable gasoline from aqueous phase hydrodeoxygenation of aqueous sugar solutions prepared by hydrolysis of maple wood [J].

Li, Ning ;

Tompsett, Geoffrey A. ;

Zhang, Taiying ;

Shi, Jian ;

Wyman, Charles E. ;

Huber, George W. .

GREEN CHEMISTRY, 2011, 13 (01) :91-101

[20] Cellulose conversion into polyols catalyzed by reversibly formed acids and supported ruthenium clusters in hot water [J].

Luo, Chen ;

Wang, Shuai ;

Liu, Haichao .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (40) :7636-7639

← 1 2 3 4 →