Synthesis and dihydrogen phosphate binding properties of pyrrole containing ansa-ferrocenes

被引：20

作者：

Sessler, JL ^{[1
]}

Zimmerman, RS ^{[1
]}

Kirkovits, GJ ^{[1
]}

Gebauer, A ^{[1
]}

Scherer, M ^{[1
]}

机构：

[1] Univ Texas, Inst Cellular & Mol Biol, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 637卷

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

ferrocene; phosphate binding; amide coupling; binding constants; pyrrole; electrochemical sensor;

D O I：

10.1016/S0022-328X(01)00931-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pyrrole-substituted alpha,omega -diamines varying in length and number of heteroatoms between the amine functionalities were reacted with 1,1'-ferrocenedimethanol to form ansa-ferrocenes. H-1-NMR binding studies in a 2% dimethylsulfoxide-d(6) solution of dichloromethane-d(2) establish a correlation between the affinity for tetrabutylammonium dihydrogen phosphate and the number of heteroatoms in the diamine. Further support for this conclusion came from electrochemical analyses. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：343 / 348

页数：6

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