A study on the effect of PVDF on the structural and transport properties of polyaniline

被引:5
作者
Jisha, P. [1 ]
Suma, M. S. [2 ]
Murugendrappa, M., V [3 ]
Raj, Kalyan [4 ]
机构
[1] BMS Coll Engn, Dept Elect & Commun Engn, Bull Temple Rd, Bangalore 560019, Karnataka, India
[2] BMS Coll Engn, Dept Med Elect, Bangalore, Karnataka, India
[3] BMS Coll Engn, Dept Phys, Bangalore, Karnataka, India
[4] BMS Coll Engn, Dept Chem, Bangalore, Karnataka, India
关键词
Polyaniline; PVDF; AC conductivity; dielectric loss; nanocomposite; POLY(VINYLIDENE FLUORIDE); DIELECTRIC PERFORMANCE;
D O I
10.1080/1023666X.2020.1779431
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The polymer composite of electrically conducting polyaniline with polyvinylidene fluoride is prepared to study the electrical conductivity and structural modifications. The electrical conductivity studies were made by varying frequency from 100 Hz to 5 MHz at room temperature. The AC conductivity remained almost constant at lower frequencies and for higher frequencies the conductivity increased. The PAni-PVDF composite exhibited better conductivity in comparison to the pure samples. The changes in dielectric properties against frequency variations were studied and exponential reduction in dielectric loss at very low frequencies was observed. The structural and morphological studies were carried out using XRD, FTIR, and SEM.
引用
收藏
页码:176 / 187
页数:12
相关论文
共 26 条
[1]  
Abd Razak S. I., 2014, MAL J FUND APPL SCI, V9, P74
[2]   Preparation and characterization of poly(vinylidene fluoride): A high dielectric performance nano-composite for electrical storage [J].
Abdalla, S. ;
Obaid, A. ;
Al-Marzouki, F. M. .
RESULTS IN PHYSICS, 2016, 6 :617-626
[3]   Doping of polyaniline films with organic sulfonic acids in aqueous media and the effect of water on these doped films [J].
Ayad, Mohamad M. ;
Zaki, Eman A. .
EUROPEAN POLYMER JOURNAL, 2008, 44 (11) :3741-3747
[4]   Polyaniline: Synthesis, Properties, and Application [J].
Boeva, Zh. A. ;
Sergeyev, V. G. .
POLYMER SCIENCE SERIES C, 2014, 56 (01) :144-153
[5]   Morphological and Structural Analysis of Polyaniline and Poly(o-anisidine) Layers Generated in a DC Glow Discharge Plasma by Using an Oblique Angle Electrode Deposition Configuration [J].
Butoi, Bogdan ;
Groza, Andreea ;
Dinca, Paul ;
Balan, Adriana ;
Barna, Valentin .
POLYMERS, 2017, 9 (12)
[6]   A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR [J].
Cai, Xiaomei ;
Lei, Tingping ;
Sun, Daoheng ;
Lin, Liwei .
RSC ADVANCES, 2017, 7 (25) :15382-15389
[7]   Electrical, optical and dielectric properties of HCl doped polyaniline nanorods [J].
Chutia, P. ;
Kumar, A. .
PHYSICA B-CONDENSED MATTER, 2014, 436 :200-207
[8]  
Deshpande N., 2016, J. At. Mol. Condens. Nano Phys., V3, P27, DOI DOI 10.26713/JAMCNP.V3I1.347
[9]  
Kalyane S., 2017, INT J PURE APPL PHYS, V13, P201
[10]   Effect of filler size on thermophysical and electrical behavior of nanocomposites based on expanded graphite nanoparticles filled in low-density polyethylene matrix [J].
Kratochvila, Jan ;
Boudenne, Abderrahim ;
Krupa, Igor .
POLYMER COMPOSITES, 2013, 34 (02) :149-155