Optical and Scintillation Properties of Eu-doped Calcium Orthoborate

被引:3
作者
Fujimoto, Y. [1 ]
Futami, Y. [1 ]
Yanagida, T. [1 ]
Kurosawa, S. [1 ]
Kawaguch, N. [3 ]
Fukuda, K. [3 ]
Totsuka, D. [4 ]
Yoshikawa, A. [1 ,2 ]
机构
[1] Tohoku Univ, IMR, Aoba Ku, 2-1-1 Katahira, Sendai, Miyagi 9808577, Japan
[2] Tohoku Univ, NICHE, Aoba Ku, Sendai, Miyagi 9808577, Japan
[3] Tokuyama Corp, Shibuya Ku, Tokyo 1508383, Japan
[4] NIHON KESSHO KOGAKU CO LTD, Gunma 3740047, Japan
来源
MATERIALS INTEGRATION | 2012年 / 508卷
关键词
scintillator; borate; luminescence; single crystal;
D O I
10.4028/www.scientific.net/KEM.508.235
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Single crystals of Eu-doped calcium orthoborate have been grown by micro-pulling (mu-PD) technique with radio frequency heating system, and its transmittance, photoluminescence and radiation responses were investigated. In transmittance spectra, Eu-doped crystal showed broad absorption band around 200-450 nm, which is due to the complex of charge transfer (CT) transition and 4f-4f transition of Eu3+. Intense Eu2+ 5f-4f and Eu3+ 4f-4f emission peaks were observed when excited to 265 nm and 385 nm, and the calculated decay times were 230 ns and 1.5 ms, respectively. Am-241 5.5 MeV alpha-ray excited radioluminescence spectra indicated both Eu2+ 5f-4f and Eu3+ 4f-4f emission peaks.
引用
收藏
页码:235 / +
页数:2
相关论文
共 12 条
[1]   Strontium and barium iodide high light yield scintillators [J].
Cherepy, Nerine J. ;
Hull, Giulia ;
Drobshoff, Alexander D. ;
Payne, Stephen A. ;
Van Loef, Edgar ;
Wilson, Cody M. ;
Shah, Kanai S. ;
Roy, Utpal N. ;
Burger, Arnold ;
Boatner, Lynn A. ;
Choong, Woon-Seng ;
Moses, William W. .
APPLIED PHYSICS LETTERS, 2008, 92 (08)
[2]   Optical and scintillation properties of Pr3+-doped Ca3(BO3)2 single crystals [J].
Fujimoto, Y. ;
Yanagida, T. ;
Yokota, Y. ;
Kawaguchi, N. ;
Fukuda, K. ;
Totsuka, D. ;
Watanabe, K. ;
Yamazaki, A. ;
Chani, V. ;
Yoshikawa, A. .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2011, 248 (02) :444-447
[3]   Scintillation characteristics of Tm3+ in Ca3(BO3)2 crystals [J].
Fujimoto, Yutaka ;
Yanagida, Takayuki ;
Yokota, Yuui ;
Kawaguchi, Noriaki ;
Fukuda, Kentaro ;
Totsuka, Daisuke ;
Watanabe, Kenichi ;
Yamazaki, Atsushi ;
Yoshikawa, Akira .
RADIATION MEASUREMENTS, 2011, 46 (12) :1506-1508
[4]   Growth and characterization of strontium metaborate scintillators [J].
Fujimoto, Yutaka ;
Yanagida, Takayuki ;
Yokota, Yuui ;
Kawaguchi, Noriaki ;
Fukuda, Kentaro ;
Totsuka, Daisuke ;
Watanabe, Kenichi ;
Yamazaki, Atsushi ;
Yoshikawa, Akira .
OPTICAL MATERIALS, 2011, 34 (02) :444-447
[5]   Growth and characterization of Ce-doped Ca3(BO3)2 crystals for neutron scintillator [J].
Fujimoto, Yutaka ;
Yanagida, Takayuki ;
Tanaka, Hidehiko ;
Yokota, Yuui ;
Kawaguti, Noriaki ;
Fukuda, Kentaro ;
Totsuka, Daisuke ;
Watanabe, Kenichi ;
Yamazaki, Atsushi ;
Yoshikawa, Akira .
JOURNAL OF CRYSTAL GROWTH, 2011, 318 (01) :784-787
[6]  
Fukuda T., 2004, ADV MAT RES FIBER CR
[7]  
Fukuda T., 2007, ADV MAT RES SHAPED C
[8]  
Hofstadter R., 1968, U.S. Patent, Patent No. [3,373,279, 3373279]
[9]   Optical and scintillation properties of LiCaAlF6:Eu crystal [J].
Shiran, NV ;
Gektin, AV ;
Neicheva, SV ;
Kornienko, VA ;
Shimamura, K ;
Ishinose, N .
JOURNAL OF LUMINESCENCE, 2003, 102 :815-818
[10]   CRYSTAL-STRUCTURE OF CALCIUM ORTHOBORATE - REDETERMINATION [J].
VEGAS, A ;
CANO, FH ;
GARCIABLANCO, S .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (MAY15) :1416-1419